25957-50-0Relevant articles and documents
Mechanism of Asymmetric Hydrogenation. Rhodium Complexes Formed by Unsaturated Carboxylic Acids, Carboxylates, and Carboxamides
Brown, John M.,Parker, David
, p. 2722 - 2730 (1982)
α,β-Unsaturated acids displace solvent from (RR)--2,2-dimethyldioxolan>bis(methanol)rhodium cation, forming chelate complexes in which olefin and carboxylate are bound to the metal.The strength of complexation is enhance
Ene reactions with α-chloronitroso compounds: Asymmetric synthesis of N-allylhydroxylamines
Kresse, G.,Vasella, A.,Felber, H.,Ritter, A.,Ascherl, B.
, p. 295 - 298 (2007/10/02)
The α-chloronitroso mannose derivative 1 undergoes ene reactions with alkenes 2 to yield nitrone hydrochlorides 3 which may be hydrolyzed to alllylic hydroxylamines.The enophilic reativity of 1 is much higher than that of other α-chloronitroso compounds.T