261178-55-6

Basic information

• Product Name: 13-benzyloxy-13-oxotridecanoic acid
• Synonyms: 13-benzyloxy-13-oxotridecanoic acid
• CAS NO: 261178-55-6
• Molecular Weight: 334.456
• Mol File: 261178-55-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 13-benzyloxy-13-oxotridecanoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 13-benzyloxy-13-oxotridecanoic acid(261178-55-6)
• EPA Substance Registry System: 13-benzyloxy-13-oxotridecanoic acid(261178-55-6)

Safety Data

• Hazardous Substances Data: 261178-55-6(Hazardous Substances Data)

Usage

Type of compound

Synthetic compound

Classification

Derivative of fatty acids

Specific derivative

Benzyloxy derivative of tridecanoic acid

Field of application

Organic chemistry

Purpose

Research and experimental purposes

Potential applications

Pharmaceutical industry for drug development and synthesis

Properties

Interesting subject for further study and potential practical applications

Upstream product

• 100-39-0 benzyl bromide 
• 505-52-2 brassylic acid 

Downstream Products

• 261178-56-7 benzyl 11-dodecenoate 

Relevant articles and documents

Method for preparing long aliphatic chain diacid derivative and application of long aliphatic chain diacid derivative

The invention provides a method for preparing a long aliphatic chain diacid derivative. The method comprises the following steps of: (1) carrying out a cyclization reaction on long aliphatic chain diacid, the long aliphatic chain diacid having a structure as shown in a formula (A); (2) reacting the long aliphatic chain diacid cyclization product with benzyl alcohol to obtain long aliphatic chain diacid monobenzyl ester; (3) carrying out an esterification reaction on the long aliphatic chain diacid monobenzyl ester and N-hydroxysuccinimide so as to obtain long aliphatic chain diacid succinimide benzyl ester; (4) carrying out a nucleophilic addition amidation reaction on the long aliphatic chain diacid succinimide benzyl ester and a compound as shown in a formula (B) to obtain a compound as shown in a formula (C); (5) carrying out an esterification reaction on the compound as shown in the formula (C) and N-hydroxysuccinimide again so as to obtain a compound as shown in a formula (D); and (6) carrying out a debenzylation reaction on the compound shown in the formula (D) so as to obtain a compound shown in a formula (E).

Novel acyl α-pyronoids, dictyopyrone A, B, and C, from Dictyostelium cellular slime molds

For the elucidation of the diversity of secondary metabolites of Dictyostelium cellular slime molds, we investigate the constituent of three species of slime molds. From the methanol extract of their fruit bodies, we obtained three novel compounds, dictyopyrone A (1) and B (2) from D. discoideum and D. rhizoposium and dictyopyrone C (3) from D. longosporum. They possess a unique α-pyrone moiety with a side chain at the C-3 position. Their relative structures were elucidated by spectral means, and the absolute configuration was confirmed by asymmetric synthesis of 1. Since these compounds were obtained from different species of Dictyostelium slime molds, they may be a type of compound common to this genus.