26186-02-7 Usage
Description
1-Tridecyne is an organic compound characterized by its long hydrocarbon chain and a triple bond at the first carbon atom. It is a versatile building block in organic synthesis and has various applications across different industries due to its unique structural properties.
Uses
1. Used in the Chemical Industry:
1-Tridecyne is used as a synthetic intermediate for the production of unsaturated fatty acids. Its triple bond allows for further reactions and modifications, making it a valuable component in the synthesis of various organic compounds.
2. Used in Pharmaceutical Industry:
1-Tridecyne is used as a key component in the stereoselective synthesis of d-erythroand l-threo-sphinganines. These compounds are important in the development of drugs targeting various diseases, as they play a crucial role in cellular signaling and membrane stability.
3. Used in Material Science:
1-Tridecyne's unique structural properties make it a potential candidate for the development of new materials with specific properties, such as improved strength, flexibility, or chemical resistance.
4. Used in the Synthesis of Fine Chemicals:
1-Tridecyne can be employed in the synthesis of various fine chemicals, including fragrances, dyes, and specialty chemicals, due to its ability to undergo a wide range of chemical reactions.
5. Used in the Development of Advanced Materials:
1-Tridecyne's structural characteristics make it a promising candidate for the development of advanced materials with specific properties, such as improved thermal stability, electrical conductivity, or optical properties.
Check Digit Verification of cas no
The CAS Registry Mumber 26186-02-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,6,1,8 and 6 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 26186-02:
(7*2)+(6*6)+(5*1)+(4*8)+(3*6)+(2*0)+(1*2)=107
107 % 10 = 7
So 26186-02-7 is a valid CAS Registry Number.
InChI:InChI=1/C13H24/c1-3-5-7-9-11-13-12-10-8-6-4-2/h1H,4-13H2,2H3
26186-02-7Relevant articles and documents
Further Improvements of the Synthesis of Alkynes from Aldehydes
Roth, Gerald J.,Liepold, Bernd,Müller, Stephan G.,Bestmann, Hans Jürgen
, p. 59 - 62 (2004)
A highly convenient way to perform the synthesis of alkynes from aldehydes is reported. The procedure utilizes a new in situ preparation of dimethyldiazomethylphosphonate. As a consequence a commercially available reagent can now be used, circumventing a disadvantage of earlier protocols. The easy one-pot procedure avoids the use of strong bases, low temperatures and inert gas techniques.
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Lumb,Smith
, p. 5032,5034 (1952)
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In situ generation of the Ohira-Bestmann reagent from stable sulfonyl azide: Scalable synthesis of alkynes from aldehydes
Jepsen, Tue Heesgaard,Kristensen, Jesper Langgaard
, p. 9423 - 9426 (2015/02/19)
We report an improved method for in situ generation of the Ohira-Bestmann reagent. Using the recently reported bench-stable imidazole-1-sulfonyl azide as diazotransfer reagent, this new method represents a scalable and convenient approach for the transformation of aldehydes into terminal alkynes. The method features an easier workup compared to the existing in situ protocol due to increased aqueous solubility of waste products.
Fritsch-Buttenberg-Wiechell rearrangement to alkynes from gem-dihaloalkenes with lanthanum metal
Umeda, Rui,Yuasa, Takumi,Anahara, Namika,Nishiyama, Yutaka
supporting information; experimental part, p. 1916 - 1919 (2011/05/14)
The first example of the FBW rearrangement using of lanthanum metal and a catalytic amount of iodine was disclosed. When gem-diiodo- and gem-dibromoalkenes were treated with lanthanum metal in the presence of a catalytic amount of iodine, the reductive dehalogenation of these compounds smoothly proceeded to produce the corresponding alkynes in moderate to good yields.
