26456-05-3

Basic information

• Product Name: 10-METHYLACRIDINIUM PERCHLORATE
• Synonyms: 10-METHYLACRIDINIUM PERCHLORATE;10-METHYLACRIDINIUM PERCHLORATE, 98+%(T)
• CAS NO: 26456-05-3
• Molecular Formula: C₁₄H₁₂N*ClO₄
• Molecular Weight: 293.70238
• Mol File: 26456-05-3.mol
• Article Data: 13

Chemical Properties

• Melting Point: 247 °C
• Appearance: /
• CAS DataBase Reference: 10-METHYLACRIDINIUM PERCHLORATE(CAS DataBase Reference)
• NIST Chemistry Reference: 10-METHYLACRIDINIUM PERCHLORATE(26456-05-3)
• EPA Substance Registry System: 10-METHYLACRIDINIUM PERCHLORATE(26456-05-3)

Safety Data

• RIDADR: UN 1479 5.1/PG III
• HazardClass: 5.1
• PackingGroup: III
• Hazardous Substances Data: 26456-05-3(Hazardous Substances Data)

Usage

General Description

10-Methylacridinium perchlorate is an organic compound that is commonly used as a catalyst in organic synthesis reactions. It is a salt formed from the cation 10-methylacridinium and the anion perchlorate. 10-METHYLACRIDINIUM PERCHLORATE is known for its high reactivity and stability, making it suitable for a wide range of chemical reactions. It is often used in the production of pharmaceuticals, dyes, and other organic compounds. Its unique properties make it a valuable tool in the field of organic chemistry, offering efficient and reliable catalysis for various chemical transformations.

InChI:InChI=1/C14H12N.ClHO4/c1-15-13-8-4-2-6-11(13)10-12-7-3-5-9-14(12)15;2-1(3,4)5/h2-10H,1H3;(H,2,3,4,5)/q+1;/p-1

Upstream product

• 4217-54-3 9,10-dihydro-10-methylacridine 
• 85289-84-5 1-benzyl-3-cyanoquinolinium perchlorate 
• 109000-88-6 9,10-Dihydro-9-isopropyl-10-methylacridine 
• 24173-45-3 2-methyl-2-(10-methyl-9,10-dihydro-acridin-9-yl)-propionic acid methyl ester 
• 138616-15-6 9-(1-naphthylmethyl)-10-methyl-9,10-dihydroacridine 
• 138616-16-7 9-Benzhydryl-10-methyl-9,10-dihydro-acridine 
• 67-68-5 dimethyl sulfoxide 
• 123525-58-6 9-tert-butyl-10-methyl-9,10-dihydroacridine 
• 1226954-85-3 10-methylacridinyl radical 
• 948-43-6 N-methylacridinium iodide 
• 150787-21-6 9-benzyl-10-methyl-9,10-dihydroacridine 

Downstream Products

• 4217-54-3 9,10-dihydro-10-methylacridine 
• 719-54-0 10-methyl-9, 10-dihydro-9-acridinone 
• 100-52-7 benzaldehyde 
• 1066-40-6 Trimethylsilanol 
• 15519-25-2 3-(aminocarbonyl)-1-(phenylmethyl)pyridinium perchlorate 
• 138616-16-7 9-Benzhydryl-10-methyl-9,10-dihydro-acridine 
• 98-86-2 acetophenone 

Relevant articles and documents

Dehydrogenation versus oxygenation in two-electron and four-electron reduction of dioxygen by 9-alky-10-methyl-9,10-dihydroacridines catalyzed by monomeric cobalt porphyrins and cofacial dicobalt porphyrins in the presence of perchloric acid

Dehydrogenation of 10-methyl-9,10-dihydroacridine (AcrH2) by dioxygen (O2) proceeds efficiently, accompanied by the two-electron and four-electron reduction of O2 to produce H2O 2 and H2O,

Effective thermal oxidation of isopropanol by an NAD+ model

The reaction of 10-methylacridinium cation (MA+) with isopropanol in the parent alcohol medium under dark, oxygen-free, and refluxing conditions gave hydride transfer product 10-methyl-9,10-dihydroacridine (MAH). The kinetics of the alcoholic oxidation reaction, including the kinetic isotope effect and the kinetic temperature effect, were determined. Hydride transfer is involved in the rate-determining step.

Hydride, hydrogen, proton, and electron affinities of imines and their reaction intermediates in acetonitrile and construction of thermodynamic characteristic graphs (TCGs) of imines as a molecule ID card

(Chemical Equation Presented) A series of 61 imines with various typical structures were synthesized, and the thermodynamic affinities (defined as enthalpy changes or redox potentials in this work) of the imines to abstract hydride anions, hydrogen atoms, and electrons, the thermodynamic affinities of the radical anions of the imines to abstract hydrogen atoms and protons, and the thermodynamic affinities of the hydrogen adducts of the imines to abstract electrons in acetonitrile were determined by using titration calorimetry and electrochemical methods. The pure heterolytic and homolytic dissociation energies of the C=N π-bond in the imines were estimated. The polarity of the C=N double bond in the imines was examined using a linear free-energy relationship. The idea of a thermodynamic characteristic graph (TCG) of imines as an efficient Molecule ID Card was introduced. The TCG can be used to quantitatively diagnose and predict the characteristic chemical properties of imines and their various reaction intermediates as well as the reduction mechanism of the imines. The information disclosed in this work could not only supply a gap of thermodynamics for the chemistry of imines but also strongly promote the fast development of the applications of imines. 2009 American Chemical Society.

Oxidation-reduction reactions of 1,3-dithioles and their ions [7]

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