2653-89-6

Basic information

• Product Name: (but-3-en-1-yloxy)benzene
• Synonyms: (But-3-en-1-yloxy)benzene; 4-Allylmethoxybenzene; benzene, (3-buten-1-yloxy)-; But-3-en-1-yl phenyl ether; p-Allylmethoxybenzene
• CAS NO: 2653-89-6
• Molecular Formula: C₁₀H₁₂O
• Molecular Weight: 148.2017
• Mol File: 2653-89-6.mol
• Article Data: 37

Chemical Properties

• Boiling Point: 211.682°C at 760 mmHg
• Flash Point: 76.69°C
• Density: 0.938g/cm³
• Vapor Pressure: 0.262mmHg at 25°C
• Refractive Index: 1.501
• CAS DataBase Reference: (but-3-en-1-yloxy)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (but-3-en-1-yloxy)benzene(2653-89-6)
• EPA Substance Registry System: (but-3-en-1-yloxy)benzene(2653-89-6)

Safety Data

• Hazardous Substances Data: 2653-89-6(Hazardous Substances Data)

Usage

Description

(But-3-en-1-yloxy)benzene is a chemical compound characterized by a molecular formula of C10H12O. It features a benzene ring with a but-3-en-1-yloxy substituent, which is a chain of four carbon atoms with a double bond between the second and third carbon atoms, and an oxygen atom attached to the third carbon atom. (but-3-en-1-yloxy)benzene is known for its role as a chemical intermediate in the synthesis of various organic compounds and is also utilized in the production of perfumes, pharmaceuticals, and other industrial chemicals. Due to its potential flammability and hazardous nature, careful handling and storage are essential.

Uses

Used in Chemical Synthesis:
(But-3-en-1-yloxy)benzene is used as a chemical intermediate for the synthesis of various organic compounds, contributing to the development of a wide range of products in the chemical industry.
Used in Perfumery:
In the perfume industry, (but-3-en-1-yloxy)benzene is used as a component in the creation of fragrances, leveraging its unique chemical properties to enhance the scent profiles of different perfumes.
Used in Pharmaceutical Production:
(But-3-en-1-yloxy)benzene is also utilized in the production of pharmaceuticals, where it serves as a key intermediate in the synthesis of specific medicinal compounds.
Used in Industrial Chemicals:
(but-3-en-1-yloxy)benzene finds application in the broader domain of industrial chemicals, where it is employed in the manufacturing process of various products that serve different purposes across multiple industries.

Upstream product

• 57056-88-9 1-(but-3-en-1-yloxy)-2-iodobenzene 
• 87280-00-0 1‐bromo‐2‐(but-3‐en‐1‐yloxy)benzene 
• 56182-34-4 o-(but-3-enyoxy)phenyl radical 
• 131323-39-2 (β-methoxyethoxy)methyl phenyl ether 
• 762-72-1 allyl-trimethyl-silane 
• 5162-44-7 1-bromo-4-butene 
• 139-02-6 sodium phenoxide 
• 627-27-0 homoalylic alcohol 
• 108-95-2 phenol 
• 68007-30-7 1-Phenyl-6-phenoxy-1-hexanone 
• 60-29-7 diethyl ether 
• 1200-03-9 4-bromophenyl butyl ether 
• 920-39-8 isopropylmagnesium bromide 
• 95-57-8 2-monochlorophenol 

Downstream Products

• 861541-07-3 (3-bromobutoxy)benzene 
• 871899-16-0 (3,4-dibromo-butyl)-phenyl ether 
• 1126-79-0 n-butyl phenyl ether 
• 89290-78-8 2-Butoxymethyl-pyridine 
• 886462-53-9 (5,5,6,6,7,7,8,8,9,9,10,10,10-tridecafluorodecyloxy)benzene 
• 408526-93-2 2-methyl-4-phenoxy-butyronitrile 
• 22720-42-9 2-methyl-4-phenoxy-butyric acid 
• 1046834-31-4 C₁₇H₁₅NO₄S 
• 1167445-32-0 4-((phenylselanyl)methyl)chromane 
• 16982-89-1 4-methylchroman 
• 193357-58-3 1-methyl-3-phenoxypropyl chloride 
• 1239668-81-5 C₁₉H₂₁NO₅S 
• 21746-93-0 2-(2-phenoxyethyl)oxirane 
• 1352331-62-4 6-(5-methoxy-2-methylphenyl)-1-phenoxy-3-hexanol 

Relevant articles and documents

Synthesis, solid-state structures, solution behaviour and catalysis studies of nickel complexes of bis(benzimidazolin-2-ylidene)pyridine pincer ligands

N-Heterocyclic carbenenickel complexes with five- and four-coordinate geometries [(CNC)NiBr2] and [(CNC)NiBr]X (X=PF6 or BPh4) have been prepared with the pincer ligands 2,6-bis(N- octylbenzimidazolin-2-ylidene)pyridine and 2,6-bis(N-butyl-5,6- dimethoxybenzimidazolin-2-ylidene)pyridine. The addition of the n-octyl substituent significantly extends the solubility of the complexes and has allowed UV-vis solution studies of the complexes in dichloromethane and methanol. The four- and five-coordinate species exist in equilibrium in solution and this equilibrium has been explored by UV-vis studies. The complexes have also been characterized by NMR studies, and single crystal X-ray diffraction studies have been performed on [(CNC)NiBr2] (where CNC=2,6-bis(N-octylbenzimidazolin-2-ylidene)pyridine) and [(CNC)NiBr]BPh 4 (where CNC=2,6-bis(N-butyl-5,6-dimethoxybenzimidazolin-2-ylidene) pyridine).

Palladium-catalyzed anti-Markovnikov oxidative acetalization of activated olefins with iron(iii) sulphate as the reoxidant

This paper discloses the efficient palladium-catalyzed anti-Markovnikov oxidative acetalization of activated terminal olefins with iron(iii) sulfate as the reoxidant. This methodology requires mild reaction conditions and shows high regioselectivity toward anti-Markovnikov products and compatibility with a wide range of functional groups. Iron(iii) sulphate was the sole reoxidant used in this method. Various olefins like vinylarenes, aryl-allylethers, aryl or benzyl acrylates and homoallylic alcohols all reacted well providing anti-Markovnikov acetals, some of which represent orthogonally functionalized 1,3- and 1,4-dioxygenated compounds.

Application of Bifunctional 2-Amino-1,4-naphthoquinones in Visible-Light-Promoted Photocatalyst-Free Alkene Perfluoroalkyl-Alkenylation

A simple and practical photochemical strategy for intermolecular perfluoroalkyl-alkenylation of alkenes with 2-amino-1,4-naphthoquinones and perfluoroalkyl iodides has been demonstrated under visible-light irradiation. Mechanistic studies reveal that easily available 2-amino-1,4-naphthoquinone substrates can serve as efficient photosensitizers to activate perfluoroalkyl iodides through a photoredox process. Therefore, the developed radical relay reaction proceeds smoothly without additional transition metals and photocatalysts.

Nickel-catalyzed removal of alkene protecting group of phenols, alcohols via chain walking process

An efficient nickel-catalyzed removal of alkene protection group under mild condition with high functional group tolerance through chain walking process has been established. Not only phenolic ethers, but also alcoholic ethers can be tolerated with the retention of stereocenter adjacent to hydroxyl group. The new reaction brings the homoallyl group into a start of new type of protecting group.