2683-06-9

Basic information

• Product Name: 3,5-dioxo-5-phenylpentanal
• Synonyms: 3,5-dioxo-5-phenylpentanal
• CAS NO: 2683-06-9
• Molecular Weight: 190.199
• Mol File: 2683-06-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3,5-dioxo-5-phenylpentanal(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-dioxo-5-phenylpentanal(2683-06-9)
• EPA Substance Registry System: 3,5-dioxo-5-phenylpentanal(2683-06-9)

Safety Data

• Hazardous Substances Data: 2683-06-9(Hazardous Substances Data)

Upstream product

• 2397-79-7 2-phenyl-4H-pyran-4-one 

Downstream Products

• 2009-96-3 2-diazo-1-phenylbutane-1,3-dione 

Relevant articles and documents

Diazoaldehyde Chemistry, Part 2: Transdiazotization of β,γ- and β,δ-Dioxoaldehydes

Base induced ring opening reactions of 2-(substituted)-4H-pyran-4-ones (R=H, Ph) gave the corresponding 5-(substituted)-3,5-dioxopentanals, which were in turn transdiazotized with 2-azido-1-ethylpyridin-1-ium BF4.The reactions gave 5-(substituted)-2,4-bis(diazo)-3,5-dioxopentanals and 4-(substituted)-1,3-bis(diazo)-2,4-butandiones, the latter being the deformylating diazo transfer products.A two-fold deformylation product (1,3-bisdiazo-2-propanone) was observed in the reaction of 3-oxopentandial, which was also synthesized from tosyl azide and 1,5-bis(N-methyl-N-phenylamino)-trans,trans-1,4-pentadiene-3-one in low yield. 4-(substituted)-3-diazo-2,4-butandienones also formed as side products.The reactions of 4,4-dimethoxy-3-oxobutanal and ethyl 2,4-dioxobutanoate with the same azidinium salt gave 1-diazo-3,3-dimethoxy-2-propanone and ethyl 3-diazo-2-oxopropanoate respectively.