285127-26-6 Usage
General Description
2(1H)-Pyridinethione, 1-[(fluorodimethylsilyl)methyl]-6-methyl- is a chemical compound with the molecular formula C9H11FNSi. It is a derivative of 2-mercaptopyridine, containing a fluorodimethylsilyl methyl group at the 1- position and a methyl group at the 6-position. 2(1H)-Pyridinethione, 1-[(fluorodimethylsilyl)methyl]-6-methyl- has potential applications in various fields, including pharmaceuticals, agrochemicals, and materials science. It may also be used as a reagent in organic synthesis, due to the unique reactivity and properties of the fluorodimethylsilyl group. However, further research is needed to fully understand the potential uses and properties of this compound.
Check Digit Verification of cas no
The CAS Registry Mumber 285127-26-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,8,5,1,2 and 7 respectively; the second part has 2 digits, 2 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 285127-26:
(8*2)+(7*8)+(6*5)+(5*1)+(4*2)+(3*7)+(2*2)+(1*6)=146
146 % 10 = 6
So 285127-26-6 is a valid CAS Registry Number.
285127-26-6Relevant articles and documents
Modelling nucleophilic substitution at silicon in solution using hypervalent silicon compounds based on 2-thiopyridones
Bassindale, Alan R.,Parker, David J.,Taylor, Peter G.
, p. 1059 - 1066 (2007/10/03)
Halodimethylsilylmethyl derivatives of 2-thiopyridones have been prepared. The N-CH2 isomer is favoured with the 6-methylthiopyridone. 13C and 29Si chemical shifts have been used to calculate the extent of sulfur-silicon bond formation and the extent of pentacoordination. The results are consistent with the oxygen analogues and reveal that as expected sulfur is a poorer nucleophile than oxygen. The unsubstituted thiopyridone and the 5-trifluoromethyl derivative favour the S-CH2 isomer. Again the mapping of nucleophilic substitution by nitrogen is in line with sulfur and oxygen nucleophiles, but in this series nitrogen is a poorer nucleophile than expected. The results are discussed in terms of steric strain, the preferences for alkylation of the pyridones and the bond strength of coordination to silicon.
