286958-07-4

Basic information

• Product Name: (R)-2-{1-[(2S,3R)-2-(2-Benzyloxy-ethyl)-tetrahydro-pyran-3-yloxy]-vinyl}-1,4-dioxa-spiro[4.5]decane
• Synonyms: (R)-2-{1-[(2S,3R)-2-(2-Benzyloxy-ethyl)-tetrahydro-pyran-3-yloxy]-vinyl}-1,4-dioxa-spiro[4.5]decane
• CAS NO: 286958-07-4
• Molecular Weight: 402.531
• Mol File: 286958-07-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-2-{1-[(2S,3R)-2-(2-Benzyloxy-ethyl)-tetrahydro-pyran-3-yloxy]-vinyl}-1,4-dioxa-spiro[4.5]decane(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-2-{1-[(2S,3R)-2-(2-Benzyloxy-ethyl)-tetrahydro-pyran-3-yloxy]-vinyl}-1,4-dioxa-spiro[4.5]decane(286958-07-4)
• EPA Substance Registry System: (R)-2-{1-[(2S,3R)-2-(2-Benzyloxy-ethyl)-tetrahydro-pyran-3-yloxy]-vinyl}-1,4-dioxa-spiro[4.5]decane(286958-07-4)

Safety Data

• Hazardous Substances Data: 286958-07-4(Hazardous Substances Data)

Upstream product

• 286958-05-2 (2S,3R)-2-(2-Benzyloxy-ethyl)-tetrahydro-pyran-3-ol 
• 242808-58-8 (2S,3R)-2-(2-propenyl)-3-hydroxyoxane 
• 75-24-1 trimethylaluminum 
• 286958-06-3 (R)-1,4-Dioxa-spiro[4.5]decane-2-carboxylic acid (2S,3R)-2-(2-benzyloxy-ethyl)-tetrahydro-pyran-3-yl ester 
• 100-39-0 benzyl bromide 

Downstream Products

• 286958-08-5 (R)-2-[(2S,3R)-2-(2-Benzyloxy-ethyl)-tetrahydro-pyran-3-yloxy]-2-(R)-1,4-dioxa-spiro[4.5]dec-2-yl-ethanol 

Relevant articles and documents

Asymmetric synthesis of the A-ring part of ciguatoxin by the strategy based on diastereoselective hydroboration and ring closing metathesis

Asymmetric synthesis of the A-ring part of a marine toxin ciguatoxin (CTX1 B) was achieved by the strategy based on ring closing metathesis (RCM), where introduction of the C5 asymmetric center was performed by diastereocontrolled hydroboration of a vinyl