29578-46-9

Basic information

• Product Name: Silane, trimethyl(3-phenyl-2-propynyl)-
• CAS NO: 29578-46-9
• Molecular Formula: C12H16Si
• Molecular Weight: 188.345
• Mol File: 29578-46-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl(3-phenyl-2-propynyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl(3-phenyl-2-propynyl)-(29578-46-9)
• EPA Substance Registry System: Silane, trimethyl(3-phenyl-2-propynyl)-(29578-46-9)

Safety Data

• Hazardous Substances Data: 29578-46-9(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 13361-64-3 trimethyl(propargyl)silane 
• 1483-82-5 phenylethynyl chloride 
• 13170-43-9 (trimethylsilyl)methylmagnesium chloride 
• 536-74-3 phenylacetylene 
• 4206-67-1 iodo(trimethylsilyl)methane 
• 673-32-5 1-Phenylprop-1-yne 
• 75-77-4 chloro-trimethyl-silane 
• 1794-48-5 1-bromo-3-phenylprop-2-yne 

Downstream Products

• 2327-99-3 1-phenylpropadiene 
• 58040-58-7 (+/-)-(R)-but-1-yne-1,3-diyldibenzene 
• 37559-18-5 3-phenylprop-2-ynyl acetate 
• 1609350-18-6 4-phenyl-5-((trimethylsilyl)methyl)cyclohept-4-enone 
• 1609350-25-5 4-methylene-5-phenylcycloheptanone 
• 1174524-06-1 (R)-5-methyl-6-phenyl-2,3,8,8a-tetrahydroindolizin-7(1H)-one 
• 1174524-07-2 (R)-8a-(but-3-enyl)-5-methyl-6-phenyl-2,3,8,8a-tetrahydroindolizin-7(1H)-one 
• 145701-69-5 1-trimethylsilyl-1,3-bis(trimethylstannyl)-3-phenylpropadiene 
• 31683-47-3 1-(trimethylsilyl)-3-phenylprop-1-yne 
• 31650-08-5 1,3-bis(trimethylsilyl)-3-phenyl-1-propyne 
• 27064-79-5 Tris(trimethylsilyl)phenylallene 
• 85332-21-4 (3-phenylpropa-1,2-diene-1,1-diyl)bis(trimethylsilane) 

Relevant articles and documents

N-Acyliminium ion chemistry and palladium catalysis: A useful combination to obtain bicyclic heterocycles

By using N-acyliminium ion chemistry, several ω-propadienyllactams and a propadienyloxazolidine were prepared from N-acyliminium ion precursors and propargylsilanes. Treatment of these allene containing lactams and oxazolidinone with allyl halides or an a

Tethered NHC Ligands for Stereoselective Alkyne Semihydrogenations

A copper(I)-catalyzed semihydrogenation of internal alkynes has been developed. A variety of oxygen- and nitrogen-tethered N-heterocyclic carbene (NHC) complexes have been investigated, leading to a highly Z-selective transformation. The catalyst is generated from inexpensive copper(I) chloride in situ and allows catalytic semihydrogenation down to 10 bar H2.

ACTION DE SILANES PROPARGYLIQUES SUR DES DERIVES CARBONYLES α-ETHYLENIQUES

Propargylsilanes RCCCH2Si(CH3)3 easily react with dialkyl alkylidenemalonates, in the presence of TiCl4, to lead to the only product corresponding to an 1,4-addition; the reaction takes place with propargylic rearrangement.