29679-67-2

Basic information

• Product Name: 2-(diphenylphosphanyl)-N,N-dimethylethanamine
• CAS NO: 29679-67-2
• Molecular Formula: C₁₆H₂₀NP
• Molecular Weight: 257.3105
• Mol File: 29679-67-2.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 344°C at 760 mmHg
• Flash Point: 161.9°C
• Vapor Pressure: 6.77E-05mmHg at 25°C
• CAS DataBase Reference: 2-(diphenylphosphanyl)-N,N-dimethylethanamine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(diphenylphosphanyl)-N,N-dimethylethanamine(29679-67-2)
• EPA Substance Registry System: 2-(diphenylphosphanyl)-N,N-dimethylethanamine(29679-67-2)

Safety Data

• Hazardous Substances Data: 29679-67-2(Hazardous Substances Data)

Usage

Description

2-(diphenylphosphanyl)-N,N-dimethylethanamine, also known as DPEA, is a chemical compound that belongs to the class of phosphines. It is a tertiary amine with a phosphine group attached to one of its nitrogen atoms. DPEA is characterized by its ability to complex with transition metals, which makes it a versatile and valuable compound in the field of chemical research and industry.

Uses

Used in Coordination Chemistry:
2-(diphenylphosphanyl)-N,N-dimethylethanamine is used as a ligand for its ability to complex with transition metals, facilitating various chemical reactions.
Used in Catalysis:
In the field of catalysis, 2-(diphenylphosphanyl)-N,N-dimethylethanamine is used as a ligand to enhance the efficiency and selectivity of catalytic processes.
Used in Organic Synthesis:
2-(diphenylphosphanyl)-N,N-dimethylethanamine is utilized as a reagent or catalyst in organic synthesis, contributing to the formation of desired products.
Used in Homogeneous Catalysis:
As a ligand in homogeneous catalysis, 2-(diphenylphosphanyl)-N,N-dimethylethanamine is used to improve the performance of catalytic systems, ensuring a uniform reaction environment and better control over the reaction kinetics.
These applications highlight the importance of 2-(diphenylphosphanyl)-N,N-dimethylethanamine in advancing chemical processes across different industries.

Upstream product

• 107-99-3 2-(dimethylamino)ethyl chloride 
• 65567-06-8 lithium diphenylphosphide 
• 4584-46-7 (2-chloroethyl)dimethylamine hydrochloride 
• 829-85-6 diphenylphosphane 
• 15475-27-1 potassium diphenylphosphine 

Downstream Products

• 39876-73-8 (β-N,N-dimethylaminoethyl)benzyldiphenylphosphonium bromide 
• 24422-55-7 P-(N,N-dimethylaminoethyl)-P,P-diphenylphosphine oxide 
• 120691-12-5 cis{Rh(PPh₂CH₂CH₂NMe₂)2}BPh₄ 
• 96806-46-1 [PtCl(C₆H₅)((C₆H₅)2PCH₂CH₂N(CH₃)2)] 
• 72121-32-5 chlorocarbonyl(2-(diphenylphosphino)-N,N-dimethylethylamine)iridium(I) 
• 96806-50-7 [PtCl(COC₆H₅)((C₆H₅)2PCH₂CH₂N(CH₃)2)] 
• 83267-14-5 Rh(C₅(CH₃)5)Cl((CH₃)2N(CH₂)2P(C₆H₅)2)⁽¹⁺⁾*B(C₆H₅)4^(1-)=Rh(C₅(CH₃)5)Cl((CH₃)2N(CH₂)2P(C₆H₅)2)(B(C₆H₅)4) 
• 92763-47-8 PtCl((C₆H₅)2P(CH₂)2N(CH₃)2)2⁽¹⁺⁾*Cl^(1-)=(PtCl((C₆H₅)2P(CH₂)2N(CH₃)2)2)Cl 
• 240123-21-1 [(κ2-P,N)-2-(N,N-dimethylamino)ethyldiphenylphosphino]dimethylplatinum(II) 
• 200880-91-7 cis,trans-bis((2-dimethyl-aminoethyl)-diphenylphosphino)(dichloro)ruthenium(II) 
• 160758-37-2 dicarbonylbis[2-(diphenylphosphino)-N,N-dimethylethanamine]-bis-[μ-(2-methyl)-2-propanethiolato]dirhodium 
• 482583-33-5 Cu(1-diphenylphosphino-2-dimethylaminoethane)2 perchlorate 
• 436147-85-2 cis[PtPh₂((1-dimethylamino)-2-(diphenylphosphanyl)etane)] 
• 172266-57-8 Pd(CH₃)((C₆H₅)2PC₂H₄N(CH₃)2)(OCH(CF₃)2) 

Relevant articles and documents

Memory and dynamics in Pd-catalyzed allylic alkylation with P,N-ligands

The memory effect, known to exert a strong influence on selectivity in some applications of the Pd-catalyzed allylic alkylation, has been investigated for a catalytic system based on a bidentate P,N-ligand. Although this system might be expected to show s

Synthesis, crystal structure, and chromotropic properties of mixed-ligand nickel(II) complexes with 1,3-diketonate and P-N bidentate ligands

Mixed-ligand nickel(II) complexes Ni(acac)(dmap)X, [Ni(acac)(dmap)]BPh 4 (1), [Ni(acac)(dmap)]BF4 (2), and [Ni(acac)(dmap)N03] (3) (where acac = acetylacetonate and dmap = l-dimethylamino-2- diphenylphosphinoethane) have been obtaine

(1-(Dimethylamino)-2-(diphenylphosphino)ethane)(η 3-1-arylallyl)palladiuin tetrafluoroborates. Preparation, isomeric equilibria, and correlations of NMR chemical shifts with hammett substituent constants

13C NMR differences of chemical shifts (δX - δH) of allyl carbon atoms in a series of trans-(1-(diphenylphospnino)-2-(dimethylamino)ethane)(η 3-1-arylallyl)palladium tetrafluoroborates, X ranging from NO2 to OMe, correlate very well with σ Hammett constants for C-1 and with σ+ for C-3, this carbon atom being in a irons relationship with the positively charged nitrogen atom.