297767-04-5Relevant articles and documents
Dramatic enhancement of reactivity of organosilicon compounds induced by complexation of bis(allyl)silanes with fluoride ion
Shibato, Atsushi,Itagaki, Yoshifumi,Tayama, Eiji,Hokke, Yasutoshi,Asao, Naoki,Maruoka, Keiji
, p. 5373 - 5382 (2007/10/03)
New type of fluoride ion catalyzed allylation agent (1a, 1b), allenylation agent (9, 10), and alkynylation agent (17) can be successfully utilized for various carbonyl substrates. The rate acceleration is ascribable to the shift of equilibrium to the chel