29921-41-3

Basic information

• Product Name: 2-CHLORODIPHENYLMETHANE
• Synonyms: 1-Benzyl-2-chlorobenzene;Diphenylmethane, 2-chloro;2-CHLORODIPHENYLMETHANE;(ORTHO-CHLOROBENZYL)BENZENE
• CAS NO: 29921-41-3
• Molecular Formula: C₁₃H₁₁Cl
• Molecular Weight: 202.68
• Mol File: 29921-41-3.mol
• Article Data: 48

Chemical Properties

• Melting Point: 13.2 °C
• Boiling Point: 97°C 1mm
• Flash Point: 122 °C
• Appearance: /
• Density: 1,12 g/cm3
• Vapor Pressure: 0.00383mmHg at 25°C
• Refractive Index: 1.583
• CAS DataBase Reference: 2-CHLORODIPHENYLMETHANE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-CHLORODIPHENYLMETHANE(29921-41-3)
• EPA Substance Registry System: 2-CHLORODIPHENYLMETHANE(29921-41-3)

Safety Data

• Hazard Codes: Xi
• HazardClass: IRRITANT
• Hazardous Substances Data: 29921-41-3(Hazardous Substances Data)

Usage

General Description

2-Chlorodiphenylmethane, also known as chlorodiphenylmethane or benzhydrol chloride, is an organic compound with the molecular formula C13H11Cl. It is a colorless solid that is sparingly soluble in water but more soluble in organic solvents. This chemical is primarily used as an intermediate in the production of other chemicals, such as pharmaceuticals and agrochemicals. It is also used as a reactant in organic synthesis and as a building block for the creation of other organic compounds. 2-Chlorodiphenylmethane is classified as a Hazardous Substance according to the Environmental Protection Agency (EPA) and should be handled and disposed of with proper safety measures.

InChI:InChI=1/C13H11Cl/c14-13-9-5-4-8-12(13)10-11-6-2-1-3-7-11/h1-9H,10H2

Upstream product

• 101-81-5 Diphenylmethane 
• 6954-45-6 (2-chlorophenyl)(phenyl)methanol 
• 5162-03-8 (2-chlorophenyl)(phenyl)methanone 
• 100-39-0 benzyl bromide 
• 108-90-7 chlorobenzene 
• 89-98-5 2-chloro-benzaldehyde 
• 71-43-2 benzene 
• 62673-31-8 benzyl(bromo)zinc 
• 105273-35-6 1,1,2,2-Tetrafluoro-2-(1,1,2,2-tetrafluoro-ethoxy)-ethanesulfonic acid 2-chloro-phenyl ester 
• 76017-71-5 1-benzyl-5,6,8,9-tetrahydro-7-phenyldibenzoacridinium triflouromethanesulphonate 
• 780-24-5 dibenzylmercury(II) 
• 95-50-1 1,2-dichloro-benzene 
• 95-49-8 2-methylchlorobenzene 
• 94-36-0 dibenzoyl peroxide 

Downstream Products

• 2116-38-3 2-(Fluorenyl-⁽⁹⁾)-diphenylmethan 
• 115848-34-5 1-(4-(tert-butyl)benzyl)-2-chlorobenzene 
• 115848-36-7 C₁₇H₁₉Cl 
• 33781-48-5 2-Chlor-4'-acetyldiphenylmethan 
• 33356-47-7 2-trimethylsilyldiphenylmethane 
• 56153-61-8 2-benzyl-benzonitrile 
• 5162-03-8 (2-chlorophenyl)(phenyl)methanone 
• 106147-64-2 4-[2-(2-Chloro-phenyl)-2-phenyl-ethyl]-1H-imidazole 
• 779-02-2 9-methylanthracene 
• 61608-94-4 1-(2-(phenylmethyl)phenyl)ethanone 
• 854678-86-7 1-(2-benzyl-phenyl)-propan-1-one 
• 1058345-47-3 2,2,2-trichloroethyl 2-chlorobenzhydrylcarbamate 
• 101-81-5 Diphenylmethane 
• 86-73-7 9H-fluorene 

Relevant articles and documents

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Multifunctional oxygen vacancies in WO3–x for catalytic alkylation of C–H by alcohols under red-light

Surface reaction kinetics and light absorption properties of a photocatalyst are essential demands for efficiently solar to chemical energy converting. In this study, plasmonic WO3–x was firstly applied to photocatalytic alkylation of arenes under red light irradiation. The oxygen vacancies, both on the surface and in the bulk of WO3–x, allow abundant free electrons to increase carrier densities and support its LSPR using low energy photons. The surface oxygen vacancies have more functions: they not only release surface tungsten sites which ensure the chemisorption of alcohols due to the coordianation ability but also promote the activation of alcohols via an efficient transport of the holes on the neighbouring O sites to chemisorption alcohol species. In brief, the bulk oxygen vacancies provide abundant charges and the surface vacancies promote the bond adsorption and activation abilities, which ensure the high efficiency of photocatalytic alkylation of C–H.

Carbonyl and olefin hydrosilylation mediated by an air-stable phosphorus(iii) dication under mild conditions

The readily-accessible, air-stable Lewis acid [(terpy)PPh][B(C6F5)4]21 is shown to mediate the hydrosilylation of aldehydes, ketones, and olefins. The utility and mechanism of these hydrosilylations are considered.