30203-87-3

Basic information

• Product Name: Benzene, 1-chloro-4-[(4-Methylphenyl)Methyl]-
• Synonyms: Benzene, 1-chloro-4-[(4-Methylphenyl)Methyl]-;1-Chloro-4-[(4-methylphenyl)methyl]-benzene
• CAS NO: 30203-87-3
• Molecular Formula: C₁₄H₁₃Cl
• Molecular Weight: 216.70602
• Mol File: 30203-87-3.mol
• Article Data: 31

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzene, 1-chloro-4-[(4-Methylphenyl)Methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-chloro-4-[(4-Methylphenyl)Methyl]-(30203-87-3)
• EPA Substance Registry System: Benzene, 1-chloro-4-[(4-Methylphenyl)Methyl]-(30203-87-3)

Safety Data

• Hazardous Substances Data: 30203-87-3(Hazardous Substances Data)

Usage

General Description

Benzene, 1-chloro-4-[(4-methylphenyl)methyl]- is a chemical compound with a molecular formula C14H13Cl. It is a chlorinated derivative of benzene, with a chlorine atom attached to the 1 position and a 4-[(4-methylphenyl)methyl] group attached to the 4 position. Benzene, 1-chloro-4-[(4-methylphenyl)methyl]- is used in the production of pharmaceuticals, agrochemicals, and dyes. It is also used as an intermediate in the synthesis of various organic compounds. Benzene, 1-chloro-4-[(4-methylphenyl)methyl]- is considered to be a hazardous substance and should be handled with caution, as it can have harmful effects on human health and the environment.

Upstream product

• 13389-74-7 4-chloro-4'methylbenzhydrol 
• 201230-82-2 carbon monoxide 
• 624-31-7 4-tolyl iodide 
• 104-83-6 1-Chloro-4-(chloromethyl)benzene 
• 98-51-1 4-tert-butyltoluene 
• 6966-45-6 4-chlorobenzylsulfonyl chloride 
• 108-88-3 toluene 
• 71-43-2 benzene 
• 106-43-4 para-chlorotoluene 
• 94-36-0 dibenzoyl peroxide 
• 5395-79-9 4'-methyl-4-chlorobenzophenone 
• 104-88-1 4-chlorobenzaldehyde 
• 183156-72-1 N-(4-chlorobenzyl)-N-nitrosoacetamide 
• 6413-52-1 2-(4-chloro-phenyl)-[1,3]dioxane 

Downstream Products

• 1438894-52-0 p-chlorophenyl-p-methylphenylmethanol acetate 
• 1032583-08-6 N-((4-chlorophenyl)(p-tolyl)methyl)-4-methylbenzenesulfonamide 
• 5395-79-9 4'-methyl-4-chlorobenzophenone 

Relevant articles and documents

Synthesis of isoreticular zinc(II)-phosphonocarboxylate frameworks and their application in the Friedel-Crafts benzylation reaction

Three isoreticular zinc(II)-phosphonocarboxylate frameworks, namely {[Zn3(pbdc)2]·2 H3O}n (ZnPC-2), {[Zn3(pbdc)2]·Hpd·H 3O·4 H2O}n (Hpd@ZnPC-2) and {[Co su

Preparation and application of blended nickel (II) complex with bisoxazoline derived azacyclo-carbene ligand and phosphite ester ligand

The invention discloses a blended nickel (II) complex with a bisoxazoline derived azacyclo-carbene ligand and a phosphite ester ligand and application of the blended nickel (II) complex. The blended nickel (II) complex has a chemical formula of Ni(NHC)[P(OR)3]X2, in the formula, R is one of ethyl or isopropyl; X is one of bromine atoms or helium atoms; and NHC is the bisoxazoline derived azacyclo-carbene ligand. In the presence of magnesium chips, the blended nickel (II) complex with the bisoxazoline derived azacyclo-carbene ligand and the phosphite ester ligand, which is disclosed by the invention, is capable of catalyzing aromatic hydrocarbon or fluoro-aromatic hydrocarbon with low activity to have a reduction cross coupling reaction with a benzyl chloride type compound at a single temperature, then a diarylmethane compound can be generated at one step, and a novel method is provided for synthesizing diarylmethane compounds.

Visible light mediated efficient oxidative benzylic sp3 C-H to ketone derivatives obtained under mild conditions using O2

A photooxygenation of benzylic sp3 C-H reaction has been demonstrated using O2 mediated by visible light. This protocol provides a simple and mild route to obtain ketones from benzylic sp3 C-H bonds. Various benzylic sp3 C-H bonds can be transformed into the desired ketone derivatives in moderate to good yields. The 18O2 labelling experiments demonstrated that the oxygen introduced into ketone originated from dioxygen. A plausible mechanism has been proposed accordingly.