30282-14-5 Usage
Description
2-HYDROXYCYCLOHEXANONE DIMER is an organic compound that serves as a reactant in various chemical reactions and synthesis processes. It is characterized by its off-white powder appearance.
Uses
Used in Chemical Synthesis:
2-HYDROXYCYCLOHEXANONE DIMER is used as a reactant for the synthesis of substrates for tin tetrachloride mediated fragmentation to produce ynones and ynoates. This application is significant in the creation of various chemical compounds and materials.
Used in Tandem Oxidation Coupling Reactions:
In the field of chemical synthesis, 2-HYDROXYCYCLOHEXANONE DIMER is also utilized as a reactant in tandem oxidation coupling reactions with diamines. This process contributes to the formation of complex molecular structures.
Used in Asymmetric Allylic Alkylation:
2-HYDROXYCYCLOHEXANONE DIMER is employed as a reactant in asymmetric allylic alkylation of enolates, a reaction that plays a crucial role in the synthesis of enantiomerically pure compounds.
Used in Formate Reduction of Allylic Carbonates:
In the production of polypropionate systems, 2-HYDROXYCYCLOHEXANONE DIMER is used as a reactant in the formate reduction of allylic carbonates, which is an essential step in the synthesis of various organic compounds.
Overall, 2-HYDROXYCYCLOHEXANONE DIMER is a versatile reactant with applications in different areas of chemical synthesis, contributing to the development of new compounds and materials.
Synthesis Reference(s)
The Journal of Organic Chemistry, 51, p. 130, 1986 DOI: 10.1021/jo00352a002Synthetic Communications, 25, p. 3141, 1995 DOI: 10.1080/00397919508015463Tetrahedron Letters, 36, p. 3031, 1995 DOI: 10.1016/0040-4039(95)00419-D
Check Digit Verification of cas no
The CAS Registry Mumber 30282-14-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,0,2,8 and 2 respectively; the second part has 2 digits, 1 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 30282-14:
(7*3)+(6*0)+(5*2)+(4*8)+(3*2)+(2*1)+(1*4)=75
75 % 10 = 5
So 30282-14-5 is a valid CAS Registry Number.
InChI:InChI=1/C12H20O4/c13-11-7-3-1-5-9(11)15-12(14)8-4-2-6-10(12)16-11/h9-10,13-14H,1-8H2
30282-14-5Relevant articles and documents
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Duerbeck et al.
, p. 2927,2937 (1971)
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Ring-fused cyclopropanone N,O-acetals. Electrochemical preparation and their reactivities under acidic conditions
Chiba,Saitoh,Okimoto,Tanase,Yano
, p. 2516 - 2519 (2007/10/03)
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Diastereo- and enantioselective synthesis of cis-2- hydroxycyclohexanamine and corresponding ethers by asymmetric reductive amination
Lauktien, Gerhard,Volk, Franz-J,Frahm, August W.
, p. 3457 - 3466 (2007/10/03)
A series of homochiral cis-2-alkoxy- and 2-aryloxyeyclohexanamines 5b- 5e has been synthesised by means of asymmetric reductive amination of the corresponding racemic 2-oxygenated cyclohexanones 2 with ee-values ranging from 95 to >99%. The respective 2-hydroxy and 2-cyclohexyl derivatives 5g-5h have been prepared from the 2-phenoxycyclohexanamine 4e. Relative and absolute stereochemistry has been elucidated.
