30290-78-9

Basic information

• Product Name: 4-phenyl-1,2,3,4-tetrahydroquinoline
• Synonyms: 4-phenyl-1,2,3,4-tetrahydroquinoline
• CAS NO: 30290-78-9
• Molecular Weight: 209.291
• Mol File: 30290-78-9.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 4-phenyl-1,2,3,4-tetrahydroquinoline(CAS DataBase Reference)
• NIST Chemistry Reference: 4-phenyl-1,2,3,4-tetrahydroquinoline(30290-78-9)
• EPA Substance Registry System: 4-phenyl-1,2,3,4-tetrahydroquinoline(30290-78-9)

Safety Data

• Hazardous Substances Data: 30290-78-9(Hazardous Substances Data)

Upstream product

• 121194-51-2 N-(3-phenylprop-2-ynyl)benzenamine 
• 102-92-1 Cinnamoyl chloride 
• 62-53-3 aniline 
• 92573-86-9 N-[(2E)-3-phenylprop-2-en-1-yl]aniline 
• 14371-10-9 (E)-3-phenylpropenal 
• 3056-73-3 N-phenylcinnamamide 
• 2983-48-4 1-phenyl-3-(phenylamino)propan-1-one 
• 890411-58-2 1,2-diphenylazetidine 
• 7647-01-0 hydrogenchloride 
• 605-03-8 4-phenylquinoline 
• 64-17-5 ethanol 
• 7732-18-5 water 
• 100-42-5 styrene 
• 622-79-7 benzyl azide 

Downstream Products

• 605-03-8 4-phenylquinoline 
• 695143-00-1 1-Aminoacetyl-4-phenyl-1,2,3,4-tetrahydroquinoline 
• 76061-83-1 1-Guanidinoacetyl-4-phenyl-1,2,3,4-tetrahydroquinoline hydrochloride 
• 76061-98-8 1-Cyanoacetyl-4-phenyl-1,2,3,4-tetrahydroquinoline 
• 76061-90-0 1-Chloroacetyl-4-phenyl-1,2,3,4-tetrahydroquinoline 
• 111663-92-4 phenyl(4-phenyl-3,4-dihydroquinolin-1(2H)-yl)methanone 
• 27623-83-2 1-methyl-4-phenyl-1,2,3,4-tetrahydroquinoline 

Relevant articles and documents

Synthesis of 4-substituted-1,2-dihydroquinolines by means of gold-catalyzed intramolecular hydroarylation reaction of n-ethoxycarbonyl-n-propargylanilines

An alternative Au(I)-catalyzed synthetic route to functionalized 1,2-dihydroquinolines is reported. This novel approach is based on the use of N-ethoxycarbonyl protected-Npropargylanilines as building blocks that rapidly undergo the IMHA reaction affording the 6-endo cyclization product in good to high yields. In the presence of N-ethoxycarbonyl-N-propargyl-metasubstituted anilines, the regiodivergent cyclization at the ortho-/para-position is achieved by the means of catalyst fine tuning.

Cu Nanoclusters Anchored on the Metal-Organic Framework for the Hydrolysis of Ammonia Borane and the Reduction of Quinolines

Free-access active sites created and the interaction regulated between them and substrates during the heterogeneous catalysis process are crucial, which remain a great challenge. In this work, in suit reduced to afford naked Cu nanoparticles (NPs) have been anchored on the metal-organic framework (MOF), NH2-MOF, to form Cu-NH2-MOF. The strategy can precisely control the Cu NP formation with small size and uniform distribution. The Cu NP properties and MOF advantages have been integrated to create a great catalyst with multiple functions and have resulted in improving the recyclability and superb catalytic activity for the one-pot reduction of heterocycle reactions under mild conditions. The experimental and theoretical calculation results show that the superior performance should be attributed to the framework of NH2-MOF that provides large caves for substrate enrichment and the stabilization of Cu sites by the -NH2 group.

Cu-Catalyzed Aerobic Oxidation of Di-tert-butyl Hydrazodicarboxylate to Di-tert-butyl Azodicarboxylate and Its Application on Dehydrogenation of 1,2,3,4-Tetrahydroquinolines under Mild Conditions

A new class of co-catalytic system was developed with homogeneous CuI and di-tert-butyl azodicarboxylate for aerobic dehydrogenation of 1,2,3,4-tetrahydroquinolines under mild conditions. The developed co-catalytic system is consisting of di-tert-butyl azodicarboxylate-mediated dehydrogenation of 1,2,3,4-tetrahydroquinoline and aerobic oxidative regeneration of di-tert-butyl azodicarboxylate from di-tert-butyl hydrazodicarboxylate using molecular oxygen as a terminal oxidant. A variety of quinolines were efficiently synthesized by the developed Cu and di-tert-butyl azodicarboxylate co-catalytic system.