308822-37-9

Basic information

• Product Name: N-[5-azido-2-bromo-2-methyl-2-(4-methylphenyl)-1-butylidene]isopropylamine
• Synonyms: N-[5-azido-2-bromo-2-methyl-2-(4-methylphenyl)-1-butylidene]isopropylamine
• CAS NO: 308822-37-9
• Molecular Weight: 351.289
• Mol File: 308822-37-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-[5-azido-2-bromo-2-methyl-2-(4-methylphenyl)-1-butylidene]isopropylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-[5-azido-2-bromo-2-methyl-2-(4-methylphenyl)-1-butylidene]isopropylamine(308822-37-9)
• EPA Substance Registry System: N-[5-azido-2-bromo-2-methyl-2-(4-methylphenyl)-1-butylidene]isopropylamine(308822-37-9)

Safety Data

• Hazardous Substances Data: 308822-37-9(Hazardous Substances Data)

Upstream product

• 58503-62-1 1-azido-3-iodopropane 

Downstream Products

• 326893-30-5 5-bromo-5-methyl-6-(4-methylphenyl)-2,3,4,5-tetrahydropyridine 
• 64291-96-9 3-methyl-2-(4-methylphenyl)pyridine 
• 326893-32-7 6-azido-3-bromo-3-methyl-1-(4-methylphenyl)-2-hexanone 

Relevant articles and documents

Synthesis of 2,3-disubstituted pyrroles and pyridines from 3-halo-1-azaallylic anions

A new synthesis of 2,3-disubstituted pyrroles and pyridines is described. The reaction of 3-halo-1-azaallylic carbanions, regiospecifically generated from α-halogenated ketimines, with ω-iodoazides led to the regiospecific formation of ω-azido-α-haloketimines. Treatment of these functionalized imines with tin(II) chloride afforded halogenated five- and six-membered cyclic imines, which were transformed under mild conditions into 2,3-disubstituted pyrroles and pyridines. The stereoselective reduction of 2,3-dialkyl-3-chloro-1-pyrrolines to afford cis-2,3-dialkyl-3-chloropyrrolidines is also reported.