30982-08-2

Basic information

• Product Name: 2-[(Acetyloxy)methyl]-2-propenoic acid methyl ester
• Synonyms: 2-[(Acetyloxy)methyl]-2-propenoic acid methyl ester;Methyl 2-(acetoxymethyl)acrylate;Mehtyl 2-(acetoxyMethyl)acrylate;Methyl 2-(acetoxymethyl)
• CAS NO: 30982-08-2
• Molecular Formula: C₇H₁₀O₄
• Molecular Weight: 158
• Mol File: 30982-08-2.mol
• Article Data: 14

Chemical Properties

• Boiling Point: 212℃
• Flash Point: 100℃
• Appearance: /
• Density: 1.083
• Storage Temp.: 2-8°C
• CAS DataBase Reference: 2-[(Acetyloxy)methyl]-2-propenoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[(Acetyloxy)methyl]-2-propenoic acid methyl ester(30982-08-2)
• EPA Substance Registry System: 2-[(Acetyloxy)methyl]-2-propenoic acid methyl ester(30982-08-2)

Safety Data

• Hazardous Substances Data: 30982-08-2(Hazardous Substances Data)

Usage

General Description

2-[(Acetyloxy)methyl]-2-propenoic acid methyl ester is a chemical compound that belongs to the class of organic chemicals known as carboxylic acid esters, which are compounds that contain a functional group with the structure -C(=O)-O-. It is also classified as an enolester, which is an alkene with a substituent of an ester group. 2-[(Acetyloxy)methyl]-2-propenoic acid methyl ester is derived from acetic acid and propenoic acid and is used in various industrial and chemical applications. It's usually presented as a clear, colorless liquid. However, detailed properties such as its toxicity and potential environmental impact have not been widely documented, implying the need for proper handling and disposal.

Upstream product

• 71901-66-1 C₈H₁₁N₃O₆ 
• 64-19-7 acetic acid 
• 15484-46-5 methyl 2-hydroxymethylacrylate 
• 108-24-7 acetic anhydride 
• 75-36-5 acetyl chloride 
• 71901-65-0 C₈H₁₂N₂O₅ 
• 22262-60-8 methyl 3-bromo-2-(bromomethyl)propionate 
• 67-56-1 methanol 
• 627-09-8 Propargyl acetate 
• 201230-82-2 carbon monoxide 
• 50-00-0 formaldehyd 
• 107270-46-2 [α-(methoxycarbonyl)vinyl]diisobutylaluminum 

Downstream Products

• 81096-08-4 2-[((E)-Hexa-3,5-dienyl)oxymethyl]-acrylic acid methyl ester 
• 127022-47-3 methyl α-(methoxycarbonylaminomethyl)acrylate 
• 144828-47-7 (1R,2S,6R,7R,9S)-(-)-9-(tert-butyldiphenylsilyloxy)-6-<(1S)-1-hydroxy-3-methylene-4-(tert-butyldimethylsilyloxy)butyl>-3,5,8-trioxa-10-azatricyclo<7.3.1.0^2,7>tridecan-11-one 
• 800366-84-1 3-(2'-methoxycarbonyl-2'-propenyl)-5-methylindole 
• 1026729-25-8 methyl 4-(3-bromo-4,5-dimethoxyphenyl)-2-methylenebutanoate 
• 1026729-47-4 5-(5-chloro-2-methoxybenzyl)-3-methylenetetrahydro-2H-pyran-2-one 
• 113592-34-0 2-Methylen-4-phenylbutansaeure-methylester 
• 1026729-49-6 5-(2-methoxybenzyl)-3-methylenetetrahydro-2H-pyran-2-one 
• 1026729-24-7 methyl 2-methylene-4-(4-methylphenyl)butanoate 
• 1026729-19-0 methyl 4-(4-chlorophenyl)-2-methylenebutanoate 

Relevant articles and documents

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Pd-Catalyzed Cascade Reactions of Aziridines: One-Step Access to Complex Tetracyclic Amines

The combination of palladium catalysis and thermal cycloaddition is shown to transform tricyclic aziridines into complex, stereodefined tetracyclic products in a single step. This highly unusual cascade process involves a diverted Tsuji-Trost sequence leading to a surprisingly facile intramolecular Diels-Alder reaction. The starting materials are accessible on multigram scales from the photochemical rearrangement of simple pyrroles. The tetracyclic amine products can be further elaborated through routine transformations, highlighting their potential as scaffolds for medicinal chemistry.

β,γ-Diaryl α-methylene-γ-butyrolactones as potent antibacterials against methicillin-resistant Staphylococcus aureus

A selected series of racemic α-methylene-γ-butyrolactones (AMGBL) synthesized via allylboration or allylindation reactions were screened against methicillin-resistant Staphylococcus aureus (MRSA) USA300. Unlike natural AMGBLs, such as parthenolide, synthe