31044-98-1

Basic information

• Product Name: Pentane, 2,2,4-trimethyl-4-nitroso-
• Synonyms: 1-nitroso-1,1,3,3-tetramethyl-butan;2,2,4-trimethyl-4-nitroso-pentane;Nitroso-t-octane;2,2,4-tetramethyl-4-nitrosopentane;Pentane,2,2,4-trimethyl-4-nitroso;nitroso-tert-octane
• CAS NO: 31044-98-1
• Molecular Formula: C8H17NO
• Molecular Weight: 143.22700
• Mol File: 31044-98-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pentane, 2,2,4-trimethyl-4-nitroso-(CAS DataBase Reference)
• NIST Chemistry Reference: Pentane, 2,2,4-trimethyl-4-nitroso-(31044-98-1)
• EPA Substance Registry System: Pentane, 2,2,4-trimethyl-4-nitroso-(31044-98-1)

Safety Data

• Hazardous Substances Data: 31044-98-1(Hazardous Substances Data)

Upstream product

• 103258-86-2 2,4-bis(1,1,3,3-tetramethylbutyl)-2H-1,5,2,4-dioxadiazine-3,6(4H)-dione 

Downstream Products

• 83933-71-5 2-(2,2,4,4-tetramethylpyrrolidin-1-yl)-p-benzoquinone 
• 83933-63-5 N-(1,1,3,3-tetramethylbutyl)-p-benzoquinone imine N-oxide 
• 25295-92-5 2,5-bis(1,1,3,3-tetramethylbutylamino)-p-benzoquinone 
• 83933-58-8 N-phenyl-N-(1,1,3,3-tetramethylbutyl)hydroxylamine 
• 83933-59-9 N-(4-methoxyphenyl)-N-(1,1,3,3-tetramethylbutyl)hydroxylamine 

Relevant articles and documents

Synthesis and Reactions of the First Examples of the 1,5,2,4-Dioxadiazine Ring System: 2,4-Dialkyl-2H-1,5,2,4-dioxadiazine-3,6(4H)-diones

The synthesis and selected reactions of 2,4-di-tert-butyl- and 2,4-bis(1,1,3,3-tetramethylbutyl)-2H-1,5,2,4-dioxadiazine-3,6(4H)-dione are described.Phosgenation of N-tert-alkylhydroxylamines gives the carbonate compounds 2 which upon further phosgenation afford the dioxadiazines 1.Acidified silica gel is required for their purification.The dioxadiazines decompose upon heating to give the corresponding nitroso compound and the isocyanate.The ring is rapidly cleaved by nucleophiles such as dimethylamine.