310871-87-5

Basic information

• Product Name: Mo(CO)5P(C₆H₅)(C₆H₄OCH₃)2
• Synonyms: Mo(CO)5P(C₆H₅)(C₆H₄OCH₃)2
• CAS NO: 310871-87-5
• Molecular Weight: 558.335
• Mol File: 310871-87-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Mo(CO)5P(C₆H₅)(C₆H₄OCH₃)2(CAS DataBase Reference)
• NIST Chemistry Reference: Mo(CO)5P(C₆H₅)(C₆H₄OCH₃)2(310871-87-5)
• EPA Substance Registry System: Mo(CO)5P(C₆H₅)(C₆H₄OCH₃)2(310871-87-5)

Safety Data

• Hazardous Substances Data: 310871-87-5(Hazardous Substances Data)

Upstream product

• 36802-41-2 bis-(2-methoxy-phenyl)-phenyl-phosphane 
• 13939-06-5 molybdenum hexacarbonyl 

Relevant articles and documents

M(CO)6 (M = Cr, Mo, W) derivatives of (o-anisyl)diphenylphosphine, bis(o-anisyl)phenylphosphine tris(o-anisyl)phosphine and (p-anisyl)bis(o-anisyl)phosphine

Aromatic tertiary phosphine ligands having ortho-methoxy substituents reacted with Group 6 metal carbonyls to form complexes with monodentate bonding through the phosphorus atom. One tungsten hexacarbonyl derivative with two P-bonded phosphine ligands was also formed. The complexes were characterized by X-ray crystallography, 1H, 13C{1H} and 31P{1H) NMR spectroscopy, IR spectroscopy and elemental analysis. The steric properties of the ligands were studied by molecular modelling methods. Metal-phosphorus bond distances correlate with cone angles of the phosphines. (C) 2000 Elsevier Science S.A.