3112-01-4

Basic information

• Product Name: 3-Phenylbenzoylmethide
• Synonyms: 3-PHENYLACETOPHENONE;1-(3-phenylphenyl)ethanone;Ethanone, 1-[1,1'-biphenyl]-3-yl
• CAS NO: 3112-01-4
• Molecular Formula: C₁₄H₁₂O
• Molecular Weight: 196.248
• Mol File: 3112-01-4.mol
• Article Data: 5

Chemical Properties

• Melting Point: 36 °C
• Boiling Point: 347.8°Cat760mmHg
• Flash Point: 151.6°C
• Appearance: /
• Density: 1.053g/cm³
• CAS DataBase Reference: 3-Phenylbenzoylmethide(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Phenylbenzoylmethide(3112-01-4)
• EPA Substance Registry System: 3-Phenylbenzoylmethide(3112-01-4)

Safety Data

• HazardClass: IRRITANT
• Hazardous Substances Data: 3112-01-4(Hazardous Substances Data)

Usage

General Description

3-Phenylbenzoylmethide, also known as Benzenebutanoylmethide, is a chemical compound with the molecular formula C15H14O2. Its systematic name according to IUPAC standards is 1-(benzoylmethyl)-3-phenylcyclohexan-1-one. Its CAS registry number is 1809-65-9. Given its composition and structure, this compound is likely to have applications in various sectors such as pharmaceuticals, chemical research, or industrial chemistry. However, detailed information about this chemical's properties and uses is not widely available, suggesting its use or study may be relatively rare or specialized.

Upstream product

• 603-33-8 triphenylbismuthane 
• 138313-22-1 3-acetylphenyl trifluoromethanesulfonate 
• 595-90-4 tetraphenyltin(IV) 
• 2142-63-4 1-(3-Bromophenyl)ethanone 
• 591-50-4 iodobenzene 
• 214360-49-3 1-[3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-phenyl]-ethanone 
• 99-90-1 para-bromoacetophenone 
• 98-80-6 phenylboronic acid 

Downstream Products

• 23948-77-8 1,1'-biphenyl-3-ylacetic acid 
• 110826-97-6 m-phenyl-α-methylbenzylamine 
• 1026960-36-0 3-[3-biphenyl-3-yl-1-(3-trifluoromethyl-phenyl)-1H-pyrazol-4-yl]-acrylic acid 
• 1186236-72-5 N-methyl-N-phenylcarbamic acid 1-biphenyl-3-yl-vinyl ester 
• 1314023-84-1 ethyl 5-(1,1'-biphenyl-3-yl)-isoxazole-3-carboxylate 
• 1314023-87-4 5-(1,1'-biphenyl-3-yl)-isoxazole-3-carboxylic acid 
• 1314024-02-6 N-(2-(benzo[d][1,3]dioxol-5-yl)ethyl)-5-(1,1'-biphenyl-3-yl)-isoxazole-3-carboxamide 

Relevant articles and documents

Electron-deficient olefin ligands enable generation of quaternary carbons by Ni-catalyzed cross-coupling

A Ni-catalyzed Negishi cross-coupling with 1,1-disubstituted styrenyl aziridines has been developed. This method delivers valuable β-substituted phenethylamines via a challenging reductive elimination that affords a quaternary carbon. A novel electron-deficient olefin ligand, Fro-DO, proved crucial for achieving high rates and chemoselectivity for C-C bond formation over β-H elimination. This ligand is easy to access, is stable, and presents a modular framework for reaction discovery and optimization. We expect that these attributes, combined with the fact that the ligands impart distinct electronic properties to a metal, will support the invention of new transformations not previously possible using established ligands.

Direct conversion of arylamines to pinacol boronates: A metal-free borylation process

Leave the metal out: Arylboronates are produced In moderate to good yields by direct borylation of readily available aryl amines (see scheme). The reaction can be carried out under air at room temperature and transition-metal catalysis is not required. The boronate products can be used without purification in SuzukiMiyaura cross-coupling reactions. Chemical equation representation

A new palladium catalyzed protocol for atom-efficient cross-coupling reactions of?triarylbismuths with aryl halides and triflates

A new palladium catalyzed protocol for an atom-efficient cross-coupling reaction of triarylbismuths with aryl halides and triflates has been described. The palladium catalytic system with Cs2CO3 base was found to be very efficient in DMA solvent to furnish excellent yields of cross-coupled functionalized biaryls in short reaction times.