312727-69-8

Basic information

• Product Name: phenyl(2,4,6-triisopropylphenyl)iodonium trifluoromethanesulfonate
• Synonyms: phenyl(2,4,6-triisopropylphenyl)iodonium trifluoromethanesulfonate
• CAS NO: 312727-69-8
• Molecular Weight: 556.428
• Mol File: 312727-69-8.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: phenyl(2,4,6-triisopropylphenyl)iodonium trifluoromethanesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl(2,4,6-triisopropylphenyl)iodonium trifluoromethanesulfonate(312727-69-8)
• EPA Substance Registry System: phenyl(2,4,6-triisopropylphenyl)iodonium trifluoromethanesulfonate(312727-69-8)

Safety Data

• Hazardous Substances Data: 312727-69-8(Hazardous Substances Data)

Upstream product

• 1493-13-6 trifluorormethanesulfonic acid 
• 2100-22-3 1-iodo-2,4,6-triisopropylbenzene 
• 71-43-2 benzene 
• 591-50-4 iodobenzene 
• 108-67-8 1,3,5-trimethyl-benzene 
• 717-74-8 1,3,5-triisopropyl benzene 

Downstream Products

• 101-84-8 diphenylether 
• 1487158-07-5 1,3,5-tri(isopropyl)-2-phenoxybenzene 
• 40586-44-5 2,4-dimethylphenyl phenyl ether 
• 1487158-11-1 2-(2,4-dimethylphenoxy)-1,3,5-triisopropylbenzene 
• 13402-31-8 1,3,5-triisopropyl-2-nitrobenzene 
• 98-95-3 nitrobenzene 
• 127-63-9 diphenyl sulphone 
• 1416262-12-8 1,3,5-triisopropyl-2-(phenylsulfonyl)benzene 
• 3052-73-1 diethyl-dithiocarbamic acid phenyl ester 
• 16906-70-0 phenyl N,N-dimethyl dithiocarbamate 
• 15185-05-4 4-phenylcoumarin 
• 92-52-4 biphenyl 
• 24388-23-6 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole 
• 519-87-9 N,N-diphenylacetamide 

Relevant articles and documents

One-Pot C?H Functionalization of Arenes by Diaryliodonium Salts

A transition-metal-free, mild, and highly regioselective synthesis of nitroarenes from arenes has been developed. The products are obtained in a sequential one-pot reaction by nitration of iodine(III) reagents with two carbon ligands, which are formed in situ from iodine(I). This novel concept has been extended to formation of aryl azides, and constitutes an important step towards catalytic reactions with these hypervalent iodine reagents. An efficient nitration of isolated diaryliodonium salts has also been developed, and the mechanism is proposed to proceed by a [2,2] ligand coupling pathway.

Palladium(II) oxide impregnated on magnetite as a catalyst for the synthesis of 4-arylcoumarins: Via a Heck-arylation/cyclization process

Heck-arylation/cyclization was achieved using heterogeneous palladium(ii) oxide impregnated on magnetite catalyst (2.5 mol%) with a lower catalyst loading than that reported for similar processes. Ethanol was used as a non-toxic and bio-renewable solvent. Good yields were afforded using a broad range of substrates (40-98%). The catalyst could be partially recycled, and analyses confirmed the almost total reduction of palladium(ii) oxide to palladium(0) as well as the iodine poissoning effect, which is the main barrier to complete recyclability.

Metal-free n -arylation of secondary amides at room temperature

The arylation of secondary acyclic amides has been achieved with diaryliodonium salts under mild and metal-free conditions. The methodology has a wide scope, allows synthesis of tertiary amides with highly congested aryl moieties, and avoids the regioselectivity problems observed in reactions with (diacetoxyiodo)benzene.