31301-28-7 Usage
Description
4-Methyl-1,10-phenanthroline (4-Mephen) is a methyl-substituted phenanthroline, a type of heterocyclic compound with a tricyclic structure. It is commonly used as a ligand in various chemical and analytical applications due to its ability to form stable complexes with metal ions.
Uses
Used in Chemical Synthesis:
4-Methyl-1,10-phenanthroline is used as a starting material for the production of 1,10-Phenanthrolin-4-aldehyde, which is an important intermediate in the synthesis of various organic compounds and pharmaceuticals.
Used in Analytical Chemistry:
As a ligand, 4-methyl-1,10-phenanthroline is employed in analytical chemistry for the detection and determination of metal ions, particularly those of iron and cobalt. It forms colored complexes with these metal ions, which can be used for their quantitative analysis.
Used in Coordination Chemistry:
In coordination chemistry, 4-methyl-1,10-phenanthroline is used as a bidentate ligand to form complexes with various metal ions. These complexes have applications in areas such as catalysis, molecular magnetism, and the development of new materials with unique properties.
Used in Pharmaceutical Industry:
The complexes formed by 4-methyl-1,10-phenanthroline with certain metal ions have potential applications in the pharmaceutical industry, as they may exhibit biological activities such as anti-cancer, anti-inflammatory, or anti-microbial properties.
Used in Environmental Applications:
4-Methyl-1,10-phenanthroline and its metal complexes can also be utilized in environmental applications, such as the removal of heavy metal ions from contaminated water or soil, due to their high affinity for these ions.
Check Digit Verification of cas no
The CAS Registry Mumber 31301-28-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,1,3,0 and 1 respectively; the second part has 2 digits, 2 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 31301-28:
(7*3)+(6*1)+(5*3)+(4*0)+(3*1)+(2*2)+(1*8)=57
57 % 10 = 7
So 31301-28-7 is a valid CAS Registry Number.
InChI:InChI=1/C13H10N2/c1-9-6-8-15-13-11(9)5-4-10-3-2-7-14-12(10)13/h2-8H,1H3
31301-28-7Relevant articles and documents
OXIDATION-REDUCTION MECHANISMS - INNER-SPHERE AND OUTER-SPHERE ELECTRON TRANSFER IN THE REDUCTION OF IRON(III), RUTHENIUM(III), AND OSMIUM(III) COMPLEXES BY ALKYL RADICALS. MECHANISMS -
Rollick,Kochi
, p. 1319 - 1330 (2007/10/02)
Alkyl radicals are readily oxidized by the tris(phenanthroline) and tris(bipyridine) complexes ML//3**3** plus of iron(III), ruthenium(III), and osmium(III) in acetonitrile solution, the second-order rate constants easily exceeding 10**6 M** minus **1s** minus **1 at 25 degree C. Two oxidative processes are identified as (a) ligand substitution on the coordinated 1,10-phenanthroline to yield various alkylphenanthrolines and (b) cation formation to afford alkenes and N-alkylacetamides (after hydrolysis). Cation formation is characterized by extensive skeletal rearrangement of neopentyl, isobutyl, and n-propyl groups, whereas ligand substitution by the same alkyl radicals occurs without any rearrangement.
