316791-68-1Relevant articles and documents
Cascade radical cyclisations leading to steroid ring constructions. Regio- and stereo-chemical studies using ester- and fluoro-alkene substituted polyene acyl radical intermediates
Boehm, Haydn M.,Handa, Sandeep,Pattenden, Gerald,Roberts, Lee,Blake, Alexander J.,Li, Wan-Sheung
, p. 3522 - 3538 (2007/10/03)
A study of the factors affecting the regio- and stereo-selective outcomes of consecutive 6-endo-trig cyclisations of polyene acyl-radical intermediates, leading to decalone, perhydrophenanthrone, and steroid ring constructions, has been carried out. Thus,