319921-64-7

Basic information

• Product Name: (S_S,R)-(+)-4-methyl-benzenesulfinic acid [2-(2-cyano-3,5-dimethoxy-phenyl)-1-methyl-ethyl]-amide
• CAS NO: 319921-64-7
• Molecular Weight: 358.461
• Mol File: 319921-64-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S_S,R)-(+)-4-methyl-benzenesulfinic acid [2-(2-cyano-3,5-dimethoxy-phenyl)-1-methyl-ethyl]-amide(CAS DataBase Reference)
• NIST Chemistry Reference: (S_S,R)-(+)-4-methyl-benzenesulfinic acid [2-(2-cyano-3,5-dimethoxy-phenyl)-1-methyl-ethyl]-amide(319921-64-7)
• EPA Substance Registry System: (S_S,R)-(+)-4-methyl-benzenesulfinic acid [2-(2-cyano-3,5-dimethoxy-phenyl)-1-methyl-ethyl]-amide(319921-64-7)

Safety Data

• Hazardous Substances Data: 319921-64-7(Hazardous Substances Data)

Upstream product

• 13321-73-8 2-bromo-1,5-dimethoxy-3-methylbenzene 
• 4179-19-5 1,3-dimethoxy-5-methylbenzene 
• 319921-60-3 2,4-dimethoxy-6-methylbenzonitrile 
• 220732-34-3 (S)-(E)-N-ethylidene-4-methylbenzenesulfinamide 

Relevant articles and documents

Sulfinimine-mediated asymmetric synthesis of 1,3-disubstituted tetrahydroisoquinolines: a stereoselective synthesis of cis- and trans-6,8-dimethoxy-1,3-dimethyl-1,2,3,4-tetrahydroisoquinoline.

[reaction: see text] The highly diastereoselective addition of lateral lithiated o-tolunitriles to sulfinimines followed by treatment of the resulting sulfinamide with MeLi, hydrolysis, and reduction represents a concise new methodology for the asymmetric