32042-39-0

Basic information

• Product Name: prop-2-yn-1-yl formate
• Synonyms: 2-propyn-1-ol, formate; Prop-2-yn-1-yl formate
• CAS NO: 32042-39-0
• Molecular Formula: C₄H₄O₂
• Molecular Weight: 84.0734
• Mol File: 32042-39-0.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 93.1°C at 760 mmHg
• Flash Point: 10.9°C
• Density: 1.025g/cm³
• Vapor Pressure: 50.2mmHg at 25°C
• Refractive Index: 1.41
• CAS DataBase Reference: prop-2-yn-1-yl formate(CAS DataBase Reference)
• NIST Chemistry Reference: prop-2-yn-1-yl formate(32042-39-0)
• EPA Substance Registry System: prop-2-yn-1-yl formate(32042-39-0)

Safety Data

• Hazardous Substances Data: 32042-39-0(Hazardous Substances Data)

Upstream product

• 64-18-6 formic acid 
• 107-19-7 propargyl alcohol 
• 134965-38-1 Hex-1-en-2-yl formate 

Downstream Products

• 64-18-6 formic acid 
• 107-19-7 propargyl alcohol 

Relevant articles and documents

Method for preparing formate-type compound

The invention discloses a method for preparing a formate-type compound. The method comprises the following steps of: adopting an alcohol-type compound and 1,3-dihydroxyacetone as reaction raw materials, and under the existence of a composite catalyst and an oxidant, reacting for 2-48 hours in a reaction medium in a reactor at a reaction temperature of 25-100 DEG C so as to obtain the formate-typecompound. The method disclosed by the invention is simple, and is mild in reaction condition, and by the method, a target product can be obtained by low cost and high yield; the used catalyst has highcatalytic activity, and is easily separated from a reaction system to be repeatedly used; the whole process is environment-friendly, and the reaction raw material (1,3-dihydroxyacetone) is easily converted from a side product (glycerol) of biodiesel, so that the utilization of the glycerol is promoted.

WATER SOLUBLE ESTERS OF [N-(4-AMINO-2-BUTYNYL)] WITH ANTICANCER ACTIVITY

The present invention relates to water soluble esters of [N-(4-amino-2-butynyl)] or 4-(N-substituted amino)-2-butynyl-1-esters and methods for production of said esters and the use of the esters for treatment of cancer.

Enol Formates: Ruthenium Catalysed Formation and Formylating Reagents

The one-step synthesis of the enol formates, isopropenyl, hex-1-en-2-yl, and α-methylenebenzyl formates, directly from terminal alkynes and formic acid with arene-ruthenium(II) catalysts is reported.They have been shown to be effective formylating reagents, under mild and neutral conditions, to produce formamides from primary and secondary amines, formylamino esters, and in the presence of a catalytic amount of imidazole, formates from alcohols or phenols.