32150-25-7

Basic information

• Product Name: Methanimidamide, N,N-dimethyl-N'-propyl-
• CAS NO: 32150-25-7
• Molecular Formula: C6H14N2
• Molecular Weight: 114.191
• Mol File: 32150-25-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Methanimidamide, N,N-dimethyl-N'-propyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanimidamide, N,N-dimethyl-N'-propyl-(32150-25-7)
• EPA Substance Registry System: Methanimidamide, N,N-dimethyl-N'-propyl-(32150-25-7)

Safety Data

• Hazardous Substances Data: 32150-25-7(Hazardous Substances Data)

Upstream product

• 6281-94-3 N-propyl formamide 
• 5815-08-7 tert-Butoxybis(dimethylamino)methane 

Relevant articles and documents

Orthoamides, XXXII. - Reactions of tert-Butoxy-N,N,N',N'-tetramethylmethanediamine with NH- and CH-acidic Compounds

tert-Butoxy-N,N,N',N'-tetramethylmethanediamine (1) reacts with N-formylglycine ethyl ester (2) and with N-formyl-β-alanine ethyl ester (9) to form the aminomethylene compounds 3 and 10, respectively.Glycine ester is aminomethylenated by 1 at the acidic NH2 group to give the amidine 6.Dimethylaminoformaldehyde dimethyl acetal (5) is also suitable for this reaction.On reaction with 1 the compounds 3 as well as 6 yield the amidine 4.N-Monosubstituted formamides are transformed by 1 into formamidines 13.Reaction of isocyanoacetate 17 and 1 affords the enamine 18, whereas reaction of benzyl isonitrile with 1 gives the amidine 19. 2-Alkyl-Δ2-oxazolines 21, carboximidates 23, 25, and amidines 27 are aminomethylenated by 1 to yield the products 22, 24, 26, and 28, respectively.The vinylogous guanidinium salt 34 is obtained by reaction of 1 with N,N,N',N'-tetramethylacetamidinium tetrafluoroborate (31a).Phosphonates 36 react with 1 to afford the enamines 37.The reaction of 1 on ethyl trimethylsilylacetate (39) gives rise to formation of ethyl 3-dimethylaminoacrylate (11).