32366-25-9

Basic information

• Product Name: 1-Azidoethylbenzene
• Synonyms: (1-Azidoethyl)benzene;1-Azidoethylbenzene;1-Phenylethyl azide
• CAS NO: 32366-25-9
• Molecular Formula: C₈H₉N₃
• Molecular Weight: 148.1846
• Mol File: 32366-25-9.mol
• Article Data: 63

Chemical Properties

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Appearance: /
• Density: g/cm³
• CAS DataBase Reference: 1-Azidoethylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Azidoethylbenzene(32366-25-9)
• EPA Substance Registry System: 1-Azidoethylbenzene(32366-25-9)

Safety Data

• Hazardous Substances Data: 32366-25-9(Hazardous Substances Data)

Usage

Physical state

Colorless to pale yellow liquid

Odor

Sweet, floral

Uses

a. Chemical intermediate in the production of pharmaceuticals
b. Chemical intermediate in the production of dyes
c. Chemical intermediate in the production of other organic compounds
d. Potential precursor for the synthesis of azido-containing polymers and materials
e. Reagent in organic synthesis

Hazardous properties

Explosive

Safety precautions

Handle with caution due to explosive properties

InChI:InChI=1/C8H10N3/c1-7(10-11-9)8-5-3-2-4-6-8/h2-7,9H,1H3/q+1

Upstream product

• 100-42-5 styrene 
• 100-41-4 ethylbenzene 
• 672-65-1 (1-chloroethyl)benzene 
• 4648-54-8 trimethylsilylazide 
• 585-71-7 (1-bromoethyl)benzne 
• 3886-69-9 (R)-1-phenyl-ethyl-amine 
• 105966-39-0 2-(1-phenylethoxy)-tetrahydro-2H-pyran 
• 93-92-5 1-phenylethyl acetate 
• 618-36-0 rac-methylbenzylamine 
• 25236-63-9 1-phenylethyl mesylate 
• 329976-80-9 potassium (1-phenylethyl)trifluoroborate 
• 769-59-5 3-phenyl-butan-2-one 
• 76-05-1 trifluoroacetic acid 
• 92976-56-2 tert-butyldimethyl(1-phenylethoxy)silane 

Downstream Products

• 13280-20-1 1-phenylethanimine 
• 6052-11-5 N-ethylideneaniline 
• 622-29-7 N-Benzylidenemethylamine 
• 3480-59-9 N-(1-phenylethyl)benzamide 
• 147169-48-0 (R,S)-N-(tert-butyloxycarbonyl)-α-methylbenzylamine 
• 25102-87-8 N-(α-methyl)benzylidene 1-phenylethanamine 
• 65370-31-2 bis(1-phenylethyl)methanediimine 
• 1721-92-2 2-methyl-4-phenylquinoline 
• 618-36-0 rac-methylbenzylamine 
• 13466-32-5 acetophenone dimethylhydrazone 
• 129575-56-0 (R)-α-methylbenzyl azide 
• 31002-29-6 (S)-α-azidoethylbenzene 

Relevant articles and documents

Metal-Free Fast Azidation by Using Tetrabutylammonium Azide: Effective Synthesis of Alkyl Azides and Well-Defined Azido-End Polymethacrylates

An effective method to synthesize azido-end polymethacrylates from tetrabutylammonium azide (BNN3) in a nonpolar solvent (toluene) was developed. Several low-mass alkyl halides were reacted with BNN3 in toluene as model reactions and

Facile Direct Coupling Reactions of MOM-protected Benzylic Alcohols Using Aluminum Chloride

MOM group is one of the most commonly used protecting groups for alcohols. This study describes novel direct functionalization of the MOM-protected benzylic alcohols. Preparation of allylic compounds from benzyl MOM ethers was successfully achieved by utilization of allyltrimethylsilane and AlCl3. In addition, direct azidation of benzyl MOM ethers using TMSN3 was successful carried out under AlCl3-mediated reaction conditions. These results demonstrate that this novel synthetic procedure is a promising approach to direct functionalization of MOM-protected alcohols including allylation and azidation.

Direct AlCl3-catalyzed transformation of benzyl THP ethers and allyl benzyl ethers

THP and allyl groups are frequently used for the protection of alcohols. In this study, novel direct transformations of benzyl THP ethers and allyl benzyl ethers, protected forms of alcohols, are reported. TMSN3 and AlCl3 were employ