32755-45-6Relevant articles and documents
From isonitrile to nitrile via ketenimine intermediate: Palladium-catalyzed 1,1-carbocyanation of allyl carbonate by α-isocyanoacetate
Qiu, Guanyinsheng,Sornay, Charlotte,Savary, David,Zheng, Sheng-Cai,Wang, Qian,Zhu, Jieping
supporting information, p. 6966 - 6971 (2018/11/03)
A palladium-catalyzed 1,1-carbocyanation of allyl carbonate by α-quaternary α-isocyanoacetate was developed. Formation of ketenimine followed by homolysis of the C–N bond and recombination of the resulting caged radical pair was proposed to account for the formation of the unusual coupling product, the β-cyano-γ,δ-unsaturated ester.