329279-60-9

Basic information

• Product Name: benzoylhydrazido^(2-)tris(diethyldithiocarbamato)molybdenum(V)
• CAS NO: 329279-60-9
• Molecular Weight: 674.897
• Mol File: 329279-60-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: benzoylhydrazido^(2-)tris(diethyldithiocarbamato)molybdenum(V)(CAS DataBase Reference)
• NIST Chemistry Reference: benzoylhydrazido^(2-)tris(diethyldithiocarbamato)molybdenum(V)(329279-60-9)
• EPA Substance Registry System: benzoylhydrazido^(2-)tris(diethyldithiocarbamato)molybdenum(V)(329279-60-9)

Safety Data

• Hazardous Substances Data: 329279-60-9(Hazardous Substances Data)

Upstream product

• 19680-83-2 bis(N,N-diethyldithiocarbamato)dioxomolybdenum(VI) 
• 613-94-5 benzoic acid hydrazide 
• 20624-25-3 sodium diethyldithiocarbamate trihydrate 

Relevant articles and documents

Tris(dialkyldithiocarbamato)diazenido(1-) and hydrazido(2-) molybdenum complexes: Synthesis and reactivity in acid medium

A series of new molybdenum complexes, [Mo(NNH-CO-Ph){S2CN (C2H5)2}3] (1), [Mo(NN-CO-C6H4-NO2){S2CN (C2H5)2}3] (2), [Mo(NNH-CO-Ph){S2CN(CH3)2}3] (3), [Mo(NN-CO-C6H4-NO2){S2CN (CH3)2}3] (4) have been synthesized, with p-nitrobenzoyldiazenido(1-) and benzoylhydrazido(2-) as ligands, and dialkyldithio-carbamatos as coligands. Reactions of these compounds with aqueous and methanolic HCl were carried out but the attempted separation of the aroyl group was unsuccessful. Only the reaction of 1 and 2 with HCl in methanol gave a product, identified as [Mo{S2CN(C2H5)2}4] [MoCl4(OCH3)2]. The complexes were characterized by elemental analysis, IR spectroscopy, 1H and 13C NMR, and mass spectrometry. Single crystals of 2 were obtained and the crystal structure was determined. The Mo atom is heptacoordinated; one diazenido(1-) and three diethyldithiocarbamatos act as ligands. From the latter one sulfur is in trans-position to the diazenido-nitrogen atom and the other five sulfur atoms lie in a plane giving a distorted pentagonal-bipyramidal coordination.