3316-22-1

Basic information

• Product Name: 1,3-bis-(2-nitropropenyl)benzene
• Synonyms: 1,3-bis-(2-nitropropenyl)benzene
• CAS NO: 3316-22-1
• Molecular Weight: 248.238
• Mol File: 3316-22-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,3-bis-(2-nitropropenyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-bis-(2-nitropropenyl)benzene(3316-22-1)
• EPA Substance Registry System: 1,3-bis-(2-nitropropenyl)benzene(3316-22-1)

Safety Data

• Hazardous Substances Data: 3316-22-1(Hazardous Substances Data)

Upstream product

• 86896-46-0 1-[3-(2-oxopropyl)phenyl]propan-2-one 
• 79-24-3 Nitroethane 
• 626-19-7 Isophthalaldehyde 

Relevant articles and documents

Palladium-catalyzed synthesis of substituted nitroolefins

A one-pot protocol toward several substituted nitroolefins 4 and 6 starting with substituted acetones 2 and 5 was described. A facile process was carried out for the triflation of substituted acetones 2 and 5 with triflic anhydride (Tf2O) under the basic condition (Cs2CO3) and then palladium-catalyzed cross-coupling of enol triflates 3 with NaNO 2 and BINAP in the presence of phase-transfer reagents (n-Bu 4NBr) under the refluxing 1,2-dimethoxyethane (DME) in acceptable yields.