3317-67-7Relevant articles and documents
BiVO4/cobalt phthalocyanine (CoPc) nanofiber heterostructures: Synthesis, characterization and application in photodegradation of methylene blue
Liu, Guoshuai,Liu, Suwen,Lu, Qifang,Sun, Haiyan,Xiu, Zhiliang
, p. 53402 - 53406 (2014)
BiVO4/cobalt phthalocyanine (CoPc) hierarchical nanostructures were prepared. The structural and photo-chemical properties were characterized using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), scanning electron micr
Thermal characterization of doped polyaniline and its composites with CoPc
George, Sajan D.,Saravanan,Anantharaman,Venkatachalam,Radhakrishnan,Nampoori,Vallabhan
, p. 235201-1-235201-5 (2004)
Thermal diffusivity of the composites of camphor sulphonic acid (CSA) doped polyaniline (PANI) and its composites with cobalt phthalocyanine (CoPc) has been measured using open cell photoacoustic technique. Analysis of the data shows that the effective thermal diffusivity value can be tuned by varying the relative volume fraction of the constituents. It is seen that polaron assisted heat transfer mechanism is dominant in CSA doped PANI and these composites exhibit a thermal diffusivity value which is intermediate to that of CSA doped PANI and CoPc. The results obtained are correlated with the electrical conductivity and hardness measurements carried out on the samples.
Boosting the Capacitive Performance of Cobalt(II) Phthalocyanine by Non-peripheral Octamethyl Substitution for Supercapacitors?
Li, Minzhang,Ramachandran, Rajendran,Wang, Yu,Chen, Qian,Xu, Zong-Xiang
, p. 1265 - 1272 (2021)
In this paper, pristine cobalt(II) phthalocyanine (CoPc) and non-peripheral octamethyl substituted CoPc (N-CoMe2Pc) are the focus of electrochemical investigation. CoPc and N-CoMe2Pc nanorods (NR) were synthesized by a facile precipitation process from sublimated bulk phthalocyanine powders and their electrochemical properties were explored. Due to the large specific surface area, the capacitance performance of the nanorods was significantly higher than that of the sublimated powder sample. N-CoMe2Pc powder exhibited better pseudocapacity compared with CoPc powder and CoPc NR, which is attributed to enhanced charge transfer rate and improved redox activity after the introduction of octamethyl substituents on phthalocyanine ring. The maximum specific capacitance value was achieved by N-CoMe2Pc NR based electrode, exhibiting 210.2 F g–1 capacitance at 5 mV s–1 scan rate and 156.1 F g–1 at 0.25 A g-1 current density, and also showing high efficiency and satisfactory retention. These results indicate that according to proper molecular design, N-CoMe2Pc NR could be applied as the potential candidate for electrode material in supercapacitors.
Preparation of Cobalt/Sulfur/Graphite Electrocatalyst for Oxygen Reduction from Efficient Two-Electron Pathway
Mohammadian,Seyyedi,Sehatnia
, p. 1672 - 1680 (2019)
Abstract—: Graphite, the most stable carbon allotrope, is widely used for various applications due to its interesting properties. In the present work, graphite surface has been partially oxidized by concentrated hydrochloric acid (37%); then, the graphite oxide surface has been modified by a low-temperature method using sulfur and cobalt atoms to obtain a Co–S–GC catalyst. The current density passing through Co–S–GC catalyst has been higher than that passing through graphite. The novel cobalt-based catalyst has been demonstrated good performance for oxygen reduction reaction (ORR) due to the unique bio-inspired structure. The number of electrons transferred for ORR vary from 2.17 to 2.41 in a wide range of over-potentials indicating an effective 2-electron pathway form O2 to H2O2. The Tafel slope (≈30 mV dec–1) indicates significant amount of cobalt oxide on the surface of the catalyst. The catalyst durability test displays a negative shift of only 11.7 mV after 10 000 cycles for its half-wave potential (E1/2).
Mercati,Morazzoni
, p. L115 (1977)
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Eckert,Ugi
, p. C55 (1976)
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Development of a perchlorate sensor based on Co-phthalocyanine derivative by impedance spectroscopy measurements
Braik,Dridi,Ali,Abbas,Ben Ali,Errachid
, p. 77 - 86 (2015)
In this work, we have prepared a perchlorate sensor based on cobalt phthalocyanine derivative molecules. The membrane was deposited onto gold substrates using dip-coating method. Adhesion and morphological properties have been studied using contact angle measurements. Then, the sensitivity, the detection range and the detection limit were determined using electrochemical impedance spectroscopy (EIS) measurements. The sensor was also studied specificity towards interfering ions nitrate (NO3-), carbonate (CO32-) and sulfate (SO42-) to show the specificity of the membrane. The impedance behavior of the perchlorate sensor (gold/membrane) has been modeled by an equivalent electrical circuit using a modified Randles model for better understanding the phenomena present at the interface membrane/electrolyte.
Sustainable approaches to the synthesis of metallophthalocyanines in solution
Imperatori, Patrizia,Paoletti, Anna Maria,Pennesi, Giovanna,Zanotti, Gloria
supporting information, (2021/06/15)
This work aims to investigate more sustainable reaction conditions for the synthesis of metallophthalocyanines. Anisole, glycerol and their mixtures have been investigated as reaction media for the tetramerization of phthalonitriles. Acetates of three divalent first-transition metal cations, Co(II), Cu(II) and Zn(II), were used and several bases were tested, depending on the chosen substrates and reaction conditions, with a view to making the whole process more sustainable while ensuring its scalability. Unsubstituted phthalocyanines were synthesized to analyze the behavior of the different metal ions in terms of reactivity in the new reaction media, resulting in a general Cu > Co > Zn trend, while the nonpolar tetra-tert-butyl substitution was investigated to evaluate the synthesis of soluble derivatives in the new conditions. Furthermore, the potassium hydroxide (KOH)-aided statistical synthesis of the unsymmetrical 9(10), 16(17), 23(24)-tri-tert-butyl-2-iodophthalocyaninato zinc(II), starting from 4-tert-butylphthalonitrile and 4-iodophthalonitrile in a glycerol/anisole mixture, proceeded with a satisfactory 26% yield. Our results provide insights into the investigation of new reaction environments and the understanding of their strengths and weaknesses, with a view to further increasing the sustainability of the synthesis of metallomacrocycles with high added value while lowering their production cost.
Preparation method and application of monosubstituent metal phthalocyanine derivative
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Paragraph 0025-0032, (2020/07/15)
The invention provides a method for preparing a monosubstituent metal phthalocyanine derivative. According to the method, the single-substituent metal phthalocyanine derivative is prepared by directlyand fully reacting a metal salt, an organic solvent and a nitrile organic compound and is used for efficient electrocatalytic carbon dioxide reduction. The method has the following advantages: on onehand, the method is simple, few impurities exist, and the atom utilization rate is high; and on the other hand, the problems of poor product selectivity, low yield and the like caused by complex substitution reaction, more side reactions, uncertain substitution positions and quantity and other factors in the traditional preparation method are avoided.