33414-84-5

Basic information

• Product Name: Cyclohexanol, 1-(phenylethynyl)-, acetate
• CAS NO: 33414-84-5
• Molecular Formula: C16H18O2
• Molecular Weight: 242.318
• Mol File: 33414-84-5.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Cyclohexanol, 1-(phenylethynyl)-, acetate(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanol, 1-(phenylethynyl)-, acetate(33414-84-5)
• EPA Substance Registry System: Cyclohexanol, 1-(phenylethynyl)-, acetate(33414-84-5)

Safety Data

• Hazardous Substances Data: 33414-84-5(Hazardous Substances Data)

Upstream product

• 20109-09-5 1-(phenylethynyl)-1-cyclohexanol 
• 108-24-7 acetic anhydride 
• 108-94-1 cyclohexanone 
• 536-74-3 phenylacetylene 
• 71-43-2 benzene 
• 463-51-4 Ketene 

Downstream Products

• 495418-37-6 2-cyclohexylidene-2-fluoro-1-phenylethanone 
• 952527-33-2 3-cyclohexylidene-2-phenyl-acrylic acid methyl ester 
• 108953-86-2 1-(1-hydroxycyclohexyl)-2-phenyl-1,2-ethanedione 
• 102313-66-6 2-(1-acetoxy-cyclohexyl)-3-phenyl-quinoxaline 
• 132494-18-9 hydroxy-(1-hydroxy-cyclohexyl)-phenyl-acetic acid 
• 151259-68-6 1-phenyl-2-<1-(2-phenylethynyl)>cyclohexyl-1-ethanone 
• 110211-36-4 C₁₄H₁₅⁽²⁾H 
• 59643-63-9 (2-cyclohexylidene ethenyl)-benzene 

Relevant articles and documents

Palladium(II)/Lewis acid cocatalyzed oxidative annulation of 2-alkenylanilines and propargylic esters: An access to benzo[ b]azepines

An attractive approach to valuable yet synthetically challenging benzo[b]azepines was established via palladium(II)/Lewis acid cocatalyzed oxidative [5 + 2] annulation of readily available 2-alkenylanilines and propargylic esters. The protocol features mild reaction conditions and good functional group tolerance, constituting an array of benzo[b]azepines in yields of 30-75%.

Domino gold-catalyzed rearrangement and fluorination of propargyl acetates

A combination of IPrAuNTf2 as catalyst in the presence of Selectfluor has been successfully used for the high yielding synthesis of α-fluoroenones via 1,3-acyloxy rearrangement of propargyl acetates followed by Csp2-F bond formation,

Gold-catalyzed efficient preparation of linear α-haloenones from propargylic acetates

Versatile linear α-iodo- and α-bromoenones are prepared efficiently from readily accessible propargylic acetates using 2 mol % of Au(PPh3)NTf2. This reaction is easy to execute and has broad substrate scope. Good to excellent Z-selectivities are observed in the cases of propargylic acetates derived from aliphatic aldehydes.