33427-17-7

Basic information

• Product Name: Cyclohexane, 1-chloro-2-iodo-, trans-
• CAS NO: 33427-17-7
• Molecular Formula: C6H10ClI
• Molecular Weight: 244.503
• Mol File: 33427-17-7.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Cyclohexane, 1-chloro-2-iodo-, trans-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexane, 1-chloro-2-iodo-, trans-(33427-17-7)
• EPA Substance Registry System: Cyclohexane, 1-chloro-2-iodo-, trans-(33427-17-7)

Safety Data

• Hazardous Substances Data: 33427-17-7(Hazardous Substances Data)

Upstream product

• 110-83-8 cyclohexene 
• 103-26-4 Methyl cinnamate 
• 286-20-4 cyclohexane-1,2-epoxide 
• 6628-80-4 trans-2-chlorocyclohexanol 
• 7429-37-0 trans-1,2-dibromocyclohexane 
• 67-56-1 methanol 
• 76888-46-5 2-Chlorocyclohexyltellurium tri-iodide 
• 110-82-7 cyclohexane 

Downstream Products

• 542-18-7 cyclohexyl chloride 
• 110-83-8 cyclohexene 
• 6628-80-4 trans-2-chlorocyclohexanol 
• 286-20-4 cyclohexane-1,2-epoxide 
• 2707-86-0 1-chloro-2-trifluoroacetoxycyclohexane 

Relevant articles and documents

Gas-Phase Atomic Halogenation Reactions Using Iodine Monochloride

The mechanism of the photoinitiated gas-phase halogenation reactions of alkanes using iodine monochloride has been reported previously as proceeding via a radical chain process to form the corresponding alkyl chlorides.This is in marked contrast to analogous reactions with bromine-chlorine mixtures, thought to form bromine chloride, which produce alkyl bromides via a radical process.An attempt has been made to rationalize this anomaly.In this paper evidence is offered to demonstrate that under photolytic conditions, alkanes and iodine monochloride react via a radical chain process to produce initially the corresponding alkyl iodide.The reaction is shown to proceed by a chain process where the chain-carrying species is the chlorine atom.However, the reaction is complicated by further ionic reactions of the alkyl iodides, whith iodine monochloride, which produce alkyl chlorides and other polyhalogenated materials.

PYRIDINIUM DICHROMATE IN ORGANIC SYNTHESIS: A CONVENIENT OXIDATION OF OLEFIN-IODINE COMPLEXES TO α-IODO KETONES

Cyclic α-iodo ketones are obtained directly by oxidation of olefin-iodine complexes with pyridinium dichromate.

Carbon-halogen bond activation by Nickel catalyst: Synthesis of alkenes, from 1,2-dihalides

Unsaturated hydrocarbons can easily be prepared in a few seconds starting from 1,2 dibromides in the presence of a catalytic amount of Nickel diphenylphosphinoethane dichloride (NidppeCl2) and tri.n.butyl tin hydride, (TBTH) at room temperature. The dependencie of the nature of starting dihalides is investigated.

Halogenation using quaternary ammonium polyhalides XXVII.1 chloroiodination of alkenes with benzyltrimethyl-ammonium dichloroiodate

The reaction of alkenes with benzyltrimethylammonium dichloroiodate in dichloromethane gave the chloro iodo adducts in anti-stereospecific and regioselective manner; in methanol these adducts were obtained along with methanol-incorporated products.