33566-59-5

Basic information

• Product Name: 4-Ketododecanoic acid methyl ester
• Synonyms: 4-Ketododecanoic acid methyl ester;4-Ketolauric acid methyl ester;4-Oxododecanoic acid methyl ester;4-Oxolauric acid methyl ester
• CAS NO: 33566-59-5
• Molecular Formula: C₁₃H₂₄O₃
• Molecular Weight: 0
• Mol File: 33566-59-5.mol
• Article Data: 10

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-Ketododecanoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Ketododecanoic acid methyl ester(33566-59-5)
• EPA Substance Registry System: 4-Ketododecanoic acid methyl ester(33566-59-5)

Safety Data

• Hazardous Substances Data: 33566-59-5(Hazardous Substances Data)

Upstream product

• 67404-61-9 C₁₉H₃₆S₅ 
• 64-17-5 ethanol 
• 55446-76-9 n-octyl-magnesium iodide 
• 1490-25-1 succinic acid monomethylester chloride 
• 67-56-1 methanol 
• 4144-55-2 4-oxododecanoic acid 
• 118793-66-1 5-n-butyl-2-(ω-carbmethoxy)propionylthiophene 
• 84028-80-8 (E)-4-Oxo-dodec-5-enoic acid methyl ester 
• 629-27-6 1-Iodooctane 
• 201230-82-2 carbon monoxide 
• 292638-85-8 acrylic acid methyl ester 
• 17049-49-9 octylmagnesium bromide 
• 764-85-2 Nonanoyl chloride 
• 78113-07-2 Ethyl 4-ethoxycarbonyl-3-oxoundecanoate 

Downstream Products

• 4144-55-2 4-oxododecanoic acid 
• 57084-18-1 gamma-dodecalactone 
• 104-67-6 5-heptyldihydro-2(3H)-furanone 
• 69830-91-7 (R)-4-dodecanolide 
• 69830-92-8 5(S)-octyl-2(3H)-dihydrofuranone 

Relevant articles and documents

Supercritical carbon dioxide as a reaction medium for silane-mediated free-radical carbonylation of alkyl halides

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Tin-free giese reaction and the related radical carbonylation using Alkyl iodides and cyanoborohydrides

Tin-free Giese reaction and the related radical carbonylation process proceeded efficiently in the presence of sodium cyanoborohydride and tetrabutylammonium cyanoborohydride. The reaction took place chemoselectively at the carbon-iodine bond but not at the carbon-bromine and carbon-chlorine bonds. The iodine atom transfer followed by hydride reduction of the resulting carbon-iodine bond is proposed as a possible mechanism.

A new convenient synthesis of methyl 4-oxoalkanoates

Methyl 4-oxoalkanoates have been obtained in good yields by treatment of 1,2-dichloro-2-alken-4-ones with sodium carbonate in methanol followed by acid-catalyzed hydrolysis of the intermediate 5-alkyl-2,2-dimethoxy-2,3-dihydrofurans.