33584-24-6Relevant articles and documents
A Multicatalytic Approach to the Hydroaminomethylation of α-Olefins
Hanna, Steven,Holder, Jeffrey C.,Hartwig, John F.
, p. 3368 - 3372 (2019)
We report an approach to conducting the hydroaminomethylation of diverse α-olefins with a wide range of alkyl, aryl, and heteroarylamines at relatively low temperatures (70–80 °C) and pressures (1.0–3.4 bar) of synthesis gas. This approach is based on sim
Free radical mediated decarboxylation C(sp3)-N cross-coupling reaction of diacyl peroxide and nitrogen-containing nucleophilic reagent
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Paragraph 0029-0041, (2021/05/15)
The invention discloses a free radical mediated decarboxylation C(sp3)-N cross coupling reaction method of diacyl peroxide and a nitrogen-containing nucleophilic reagent. According to the method, novel diacyl peroxide is used as an alkylation reagent, dif
Alcohol Amination Catalyzed by Copper Powder as a Self-Supported Catalyst
Wu, Yajuan,Huang, Yongji,Dai, Xingchao,Shi, Feng
, p. 3185 - 3191 (2018/11/30)
Catalytic alcohol amination is a sustainable reaction for N-alkyl amine synthesis. Homogeneous and supported copper catalysts have long been studied for this reaction and have given some impressive results. In this study, copper powder is found to behave as an active catalyst for alcohol amination, giving better catalytic performance than metal-oxide-supported nanocopper catalysts. Catalyst characterization suggests that the copper powder can be considered as a self-supported nanocopper catalyst (i.e., nanocopper supported on copper particles). These results might promote the study of unsupported transition metal powders in sustainable catalytic reactions.
