33603-38-2Relevant articles and documents
Hydroindation of allenes and its application to radical cyclization
Hayashi, Naoki,Hirokawa, Yusuke,Shibata, Ikuya,Yasuda, Makoto,Baba, Akio
supporting information; experimental part, p. 1949 - 1954 (2009/01/31)
Hydroindation of allenes and radical cyclization of 1,2,7-trienes (allenenes) were accomplished by HInCl2 with high regioselectivity to afford a variety of cyclic compounds. The resulting vinylic indiums could be used for successive coupling reactions in a one-pot procedure. The use of HInCl2 generated slowly in situ is extremely effective for the radical cyclization. The Royal Society of Chemistry.