33670-50-7Relevant articles and documents
REACTION OF ORGANOBORANES WITH LEAD(IV) ACETATE AZIDE. A SYNTHESIS OF AZIDOALKANES FROM ALKENES VIA HYDROBORATION.
Masuda,Hoshi,Arase
, p. 1026 - 1030 (2007/10/02)
Trialkylboranes prepared from alkenes via hydroboration react with lead(IV) acetate azide in dichloromethane at minus 25 degree C to form the corresponding azidoalkanes in a one-pot manner. One of two of the alkyl groups of trialkylboranes are utilized in the reaction. For example, 1-azidohexane is afforded from 1-hexene in 50% yield based on the alkene employed.