33788-68-0

Basic information

• Product Name: {NiI(Tris-(3-dimethylarsino-propyl)-phosphin)}-Tetraphenylborat
• CAS NO: 33788-68-0
• Molecular Weight: 977.018
• Mol File: 33788-68-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {NiI(Tris-(3-dimethylarsino-propyl)-phosphin)}-Tetraphenylborat(CAS DataBase Reference)
• NIST Chemistry Reference: {NiI(Tris-(3-dimethylarsino-propyl)-phosphin)}-Tetraphenylborat(33788-68-0)
• EPA Substance Registry System: {NiI(Tris-(3-dimethylarsino-propyl)-phosphin)}-Tetraphenylborat(33788-68-0)

Safety Data

• Hazardous Substances Data: 33788-68-0(Hazardous Substances Data)

Upstream product

• 143-66-8 sodium tetraphenyl borate 
• 10377-51-2 lithium iodide 

Relevant articles and documents

Five-coordinate nickel(II) complexes with tris(3-dimethylarsinopropyl)phosphine

Chemical analyses, magnetic moments, electronic absorption spectra, and molar conductance values indicate that tris(3-dimethylarsinopropyl)phosphine (TAP) reacts with nickel(II) salts to form the five-coordinate cations [Ni(TAP)X]+ (where X is a monodentate anion). The aquo complex [Ni(TAP)H2O]2+ is analogous. The absorption spectra suggest that the cation has a trigonal-bipyramidal structure in which the organic molecule functions as a tetradentate ligand. The electronic absorption spectra and the chemical reactions of the complexes are discussed.