33877-16-6

Basic information

• Product Name: (R)-1-Phenylethanethiol
• Synonyms: (R)-1-PHENYLETHANETHIOL;S-α-Methyl-BenzeneMethanethiol
• CAS NO: 33877-16-6
• Molecular Formula: C₈H₁₀S
• Molecular Weight: 138.23
• Mol File: 33877-16-6.mol
• Article Data: 21

Chemical Properties

• Boiling Point: 200.2 °C at 760 mmHg
• Flash Point: 77.9 °C
• Appearance: /
• Density: 1.008 g/cm³
• CAS DataBase Reference: (R)-1-Phenylethanethiol(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-1-Phenylethanethiol(33877-16-6)
• EPA Substance Registry System: (R)-1-Phenylethanethiol(33877-16-6)

Safety Data

• Hazardous Substances Data: 33877-16-6(Hazardous Substances Data)

Usage

General Description

"(R)-1-Phenylethanethiol, also known as (R)-(-)-1-Phenylethanethiol or (R)-Alpha-Methylbenzenemethanethiol, is a colorless to light yellow liquid that possesses a strong, unpleasant odor. It is commonly used as a reagent in the synthesis of various other organic compounds, including pharmaceuticals. The (R)- designation in its name refers to the configuration of the molecule around its single chiral center, indicating that it is the right-handed or clockwise enantiomer. It's important to note, that this chemical should be handled with caution as it may cause harm if ingested or inhaled due to its toxicity. In the environment, it can cause damage to aquatic life. It has a CAS number of 34313-35-4.

Upstream product

• 52053-61-9 di(α-methylbenzyl)disulfide 
• 585-71-7 (1-bromoethyl)benzne 
• 98-86-2 acetophenone 
• 109436-90-0 Dithiophosphorsaeure-O,O'-diisopropylester-S-(α-methyl-benzylester) 
• 672-65-1 (1-chloroethyl)benzene 
• 5769-02-8 2-methyl-2-phenyl[1,3]dithiolane 
• 32362-99-5 benzylthioacetate 
• 98-85-1 1-Phenylethanol 
• 64-04-0 phenethylamine 
• 33877-15-5 (R)-(+)-styrene sulfide 
• 54810-89-8 α-Isopropylamino-α-phenylpropionitril 
• 67385-07-3 S-(1-phenylethyl) ethanethioate 
• 64-19-7 acetic acid 
• 29850-82-6 (+/-)-(S)-(1-phenyl-ethyl)-isothiourea; hydrobromide 

Downstream Products

• 86963-40-8 (R)-1-phenylethanesulfonic acid 
• 82916-73-2 (R,R)-(+)-bis(1-phenylethyl) disulfide 
• 13125-70-7 (+-)-methyl-(1-phenyl-ethyl)-sulfide 
• 50999-18-3 racem.-bis-(1-phenyl-ethyl)-disulfide 
• 103-81-1 Benzeneacetamide 
• 67385-07-3 S-(1-phenylethyl) ethanethioate 
• 345927-66-4 (2,4-dinitro-phenyl)-(1-phenyl-ethyl)-sulfide 
• 20803-99-0 racemic 2-((1-phenylethyl)thio)acetic acid 
• 91970-39-7 2,4-Dimethyl-4-phenyl-3-thia-buttersaeure 
• 69543-90-4 α-Phenaethyl-thionitrit 
• 96418-50-7 S-<α-Methyl-benzylmercapto>-thioglykolsaeure-methylester 
• 69652-49-9 1-Phenaethyl-allylsulfid 
• 42383-85-7 C₉H₁₂N₂S₂ 
• 33691-99-5 1-(1-Phenyl-ethylsulfanyl)-propan-2-one 

Relevant articles and documents

Accelerated reduction and solubilization of elemental sulfur by 1,2-aminothiols

Nucleophilic 1,2-aminothiol compounds readily reduce typically-insoluble elemental sulfur to polysulfides in both water and nonpolar organic solvents. The resulting anionic polysulfide species are stabilized through hydrogen-bonding interactions with the proximal amine moieties. These interactions can facilitate sulfur transfer to alkenes.

1-aryl ethanesulfonic acid and preparation method of its derivative

The invention provides 1-aryl ethanesulfonic acid and a preparation method of its derivative. The preparation method comprises the following steps that (a) 1-aryl halogensated ethane represented in aformula (I) and sodium hydrosulfide react to generate 1-

Ligand dependence of the synthetic approach and chiroptical properties of a magic cluster protected with a bicyclic chiral thiolate

Chiral gold clusters stabilised by enantiopure thiolates were prepared, size-selected and characterised by circular dichroism and mass spectrometry. The product distribution is found to be ligand dependent. Au25 clusters protected with camphorthiol show clear resemblance of their chiroptical properties with their glutathionate analogue. The Royal Society of Chemistry 2012.