34363-01-4Relevant articles and documents
Pines. Eschinazi
, p. 1178 (1956)
Reaction of levoglucosenone with (±)-α-terpineol and its acetate
Galimova, Yu. S.,Khalilova, Yu. A.,Sharipov, B. T.,Spirikhin, L. V.,Rameev, Sh. R.,Safiullin, R. L.,Valeev, F. A.
, p. 1848 - 1850 (2014)
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Magnesium activation of dichlorodi-η5-cyclopentadienyltitanium in the catalytic hydrogenation of olefins and acetylenes
Scott, Frederick,Raubenheimer, Helgard G.,Pretorius, Gerard,Hamese, Augustine M.
, p. C17 - C20 (1990)
Magnesium activation of dichlorodi-η5-cyclopentadienyltitanium (Cp2TiCl2) in tetrahydrofuran (THF) under a dihydrogen atmosphere has been shown to produce a stable solution which effectively hydrogenates various types of olefins and acetylenes
Continuous synthesis of menthol from citronellal and citral over Ni-beta-zeolite-sepiolite composite catalyst
Er?nen, Kari,M?ki-Arvela, P?ivi,Martinez-Klimov, Mark,Muller, Joseph,Murzin, Dmitry Yu.,Peurla, Markus,Simakova, Irina,Vajglova, Zuzana
, (2022/04/03)
One-pot continuous synthesis of menthols both from citronellal and citral was investigated over 5 wt% Ni supported on H-Beta-38-sepiolite composite catalyst at 60–70 °C under 10–29 bar hydrogen pressure. A relatively high menthols yield of 53% and 49% and stereoselectivity to menthol of 71–76% and 72–74% were obtained from citronellal and citral respectively at the contact time 4.2 min, 70 °C and 20 bar. Citral conversion noticeably decreased with time-on-stream under 10 and 15 bar of hydrogen pressure accompanied by accumulation of citronellal, the primary hydrogenation product of citral, practically not affecting selectivity to menthol. A substantial amount of defuctionalization products observed during citral conversion, especially at the beginning of the reaction (ca. 1 h), indicated that all intermediates could contribute to formation of menthanes. Ni/H-Beta-38-sepiolite composite material prepared by extrusion was characterized by TEM, SEM, XPS, XRD, ICP-OES, N2 physisorption and FTIR techniques to perceive the interrelation between the physico-chemical and catalytic properties.
Ambient Hydrogenation and Deuteration of Alkenes Using a Nanostructured Ni-Core–Shell Catalyst
Beller, Matthias,Feng, Lu,Gao, Jie,Jackstell, Ralf,Jagadeesh, Rajenahally V.,Liu, Yuefeng,Ma, Rui
supporting information, p. 18591 - 18598 (2021/06/28)
A general protocol for the selective hydrogenation and deuteration of a variety of alkenes is presented. Key to success for these reactions is the use of a specific nickel-graphitic shell-based core–shell-structured catalyst, which is conveniently prepared by impregnation and subsequent calcination of nickel nitrate on carbon at 450 °C under argon. Applying this nanostructured catalyst, both terminal and internal alkenes, which are of industrial and commercial importance, were selectively hydrogenated and deuterated at ambient conditions (room temperature, using 1 bar hydrogen or 1 bar deuterium), giving access to the corresponding alkanes and deuterium-labeled alkanes in good to excellent yields. The synthetic utility and practicability of this Ni-based hydrogenation protocol is demonstrated by gram-scale reactions as well as efficient catalyst recycling experiments.
Method for synthesizing bark beetle pheromone
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Paragraph 0026-0027; 0031-0032, (2021/09/01)
The bark beetle pheromone is (1S, 4R) -4 - isopropyl -1 - methyl -2 -cyclohexene -1 - alcohol, and the synthetic method comprises the following steps: forming a clathrate compound with (S)- (-) - limonene and carrying out catalytic hydrogenation reaction