345217-80-3Relevant articles and documents
The highly enantioselective transformation of silylketenes into α-silylthioesters catalysed by cinchona alkaloids
Blake, Alexander J.,Friend, Christopher L.,Outram, Robert J.,Simpkins, Nigel S.,Whitehead, Andrew J.
, p. 2877 - 2881 (2007/10/03)
The reaction of silylketenes with thiophenol, mediated by cinchona alkaloid catalysts, proceeds to give α-silylthioester products in good chemical yield and with enantiomeric excess values in the range 79-93%. The absolute configuration of one of the thioester products was determined by X-ray diffraction.