34649-27-9

Basic information

• Product Name: Phenol, 2,3,5-trimethyl-, acetate
• CAS NO: 34649-27-9
• Molecular Formula: C11H14O2
• Molecular Weight: 178.231
• Mol File: 34649-27-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Phenol, 2,3,5-trimethyl-, acetate(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 2,3,5-trimethyl-, acetate(34649-27-9)
• EPA Substance Registry System: Phenol, 2,3,5-trimethyl-, acetate(34649-27-9)

Safety Data

• Hazardous Substances Data: 34649-27-9(Hazardous Substances Data)

Upstream product

• 201230-82-2 carbon monoxide 
• 697-82-5 2,3,5-trimethylphenol 
• 74-88-4 methyl iodide 
• 20469-61-8 2,3,5-trimethylanisole 
• 108-24-7 acetic anhydride 
• 64-19-7 acetic acid 
• 79-21-0 peracetic acid 

Downstream Products

• 697-82-5 2,3,5-trimethylphenol 
• 163429-79-6 6-acetylisopseudocumenol 
• 186743-37-3 6-hydroxyethylallylisopseudocumenol 
• 186743-36-2 6-acetylallylisopseudocumenol 
• 186743-39-5 6-methoxyallylisopseudocumenol 
• 186743-38-4 6-hydroxyallylisopseudocumenol 
• 58972-39-7 1-(2-hydroxy-3,4,5-trimethyl-phenyl)-ethanone 

Relevant articles and documents

An efficient method to prepare aryl acetates by the carbonylation of aryl methyl ethers or phenols

Synthesis of valuable chemicals from lignin based compounds is critical for the application of biomass. Here, we develop a method of preparing aryl acetates by the carbonylation of aryl methyl ethers or phenols under low CO pressure. Good to excellent yields of aryl acetates were obtained using different substrates, and a possible reaction mechanism was proposed by conducting a series of control experiments. This method may provide a potential way for the utilization of lignin.

3-PHENOXY-4-PYRIDAZINOL DERIVATIVE AND HERBICIDE COMPOSITION CONTAINING THE SAME

A compound represented by the formula: wherein R1 represents a hydrogen atom, a halogen atom, alkyl group, etc., ???R2 represents a hydrogen atom, a halogen atom, alkyl group, etc., ???R3, R4, R5, R6 and R7 each independently represent a hydrogen atom, a halogen atom, a substitutable alkyl group, a substitutable alkenyl group, alkynyl group, a substitute-able cycloalkyl group, etc., or adjacent two of R3, R4, R5, R6 and R7 may together with the carbon atoms to which the respective substituents are bonded form a ring which may be substituted, ???m and n each independently represent 0 or 1, a salt thereof or an ester derivative thereof; an agricultural chemical containing the same as an active ingredient; and a herbicidal composition containing the compound and a second herbicidally active compound as active ingredients.

REACTION OF 1,2,4-TRIMETHYLBENZENE WITH PERACETIC ACID

The oxidation of 1,2,4-trimethylbenzene with peracetic acid leads to the formation of trimethylphenols and hydroquinones, which undergo transformations to the corresponding benzoquinones and products from oxidative cleavage of the ring.The controlling stage of the process is the electrophilic hydroxylation of 1,2,4-trimethylbenzene.