3480-96-4

Basic information

• Product Name: N,N-diallyl-p-toluidine
• Synonyms: N,N-diallyl-p-toluidine
• CAS NO: 3480-96-4
• Molecular Weight: 187.285
• Mol File: 3480-96-4.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: N,N-diallyl-p-toluidine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-diallyl-p-toluidine(3480-96-4)
• EPA Substance Registry System: N,N-diallyl-p-toluidine(3480-96-4)

Safety Data

• Hazardous Substances Data: 3480-96-4(Hazardous Substances Data)

Upstream product

• 4873-09-0 allyl tosylate 
• 106-49-0 p-toluidine 
• 123-11-5 4-methoxy-benzaldehyde 
• 106-95-6 allyl bromide 
• 100-52-7 benzaldehyde 
• 99-99-0 1-methyl-4-nitrobenzene 
• 2101-86-2 p-methylazidobenzene 
• 107-18-6 allyl alcohol 
• 6728-21-8 allyl mesylate 

Downstream Products

• 1018853-59-2 N,2-diallyl-4-methylaniline 
• 1018853-60-5 2,6-diallyl-4-methylaniline 
• 88320-36-9 2,5-dihydro-1-(4-methylphenyl)-1H-pyrrole 
• 827-60-1 1-(4-methylphenyl)-1H-pyrrole 
• 1316312-79-4 ethyl allyl-(2-allyl-4-methylphenyl)carbamate 
• 1316312-36-3 ethyl 2,6-dimethyl-2H-quinoline-1-carboxylate 
• 1316312-07-8 ethyl (2-buta-1,3-dienyl-4-methylphenyl)carbamate 

Relevant articles and documents

Highly efficient Ru(ii)-alkylidene based Hoveyda-Grubbs catalysts for ring-closing metathesis reactions

Three novel phosphine-free Ru-alkylidenes (7a-7c) have been synthesized and utilized as efficient catalysts for ring closing metathesis (RCM) reaction. Spectroscopic data, i.e. NMR and HRMS, along with single crystal X-ray diffraction analysis, were used

Facet-Dependent Catalytic Activity of Palladium Nanocrystals in Tsuji-Trost Allylic Amination Reactions with Product Selectivity

Pd nanocubes, cuboctahedra, and octahedra with good size control were used to catalyze C-N bond formation in the Tsuji-Trost allylic amination reaction of aniline. Nanocubes gave either monoallylaniline or diallylaniline depending on the amount of allyl bromide used, but the octahedra and cuboctahedra only gave mixtures of monoallylaniline and diallylaniline under the same reaction conditions. The Pd nanocubes were stable over multiple cycles of the reaction. The cubes and octahedra were demonstrated to catalyze the amination reaction by using a wide variety of substituted anilines, but the cubes were the best catalyst with consistently the highest efficiency, product yield, and product selectivity. This work demonstrates that the use of metal nanocrystals with proper facet control is important for catalyzing coupling reactions with product selectivity. Getting into shapes: Pd nanocubes, cuboctahedra, and octahedra with good size control are used to catalyze C-N bond formation in the Tsuji-Trost allylic amination reaction of aniline. The Pd nanocube catalyst gives good product selectivity, whereas the Pd octahedra and cuboctahedra catalysts yield mixtures of products under the same reaction conditions. Furthermore, Pd nanocubes are stable over multiple reaction cycles.

Highly selective N-allylation of anilines under microwave irradiation

An easy and rapid procedure for the preparation of a variety of mono- and bis-allylated anilines via the reaction of allyl bromide with a wide range of anilines under microwave irradiation is described. This approach allows use of mild conditions and short reaction times to give high selectivities and excellent yields.