351-93-9

Basic information

• Product Name: Benzene, 1-(ethenyloxy)-4-fluoro-
• CAS NO: 351-93-9
• Molecular Formula: C8H7FO
• Molecular Weight: 138.141
• Mol File: 351-93-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(ethenyloxy)-4-fluoro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(ethenyloxy)-4-fluoro-(351-93-9)
• EPA Substance Registry System: Benzene, 1-(ethenyloxy)-4-fluoro-(351-93-9)

Safety Data

• Hazardous Substances Data: 351-93-9(Hazardous Substances Data)

Upstream product

• 108-05-4 vinyl acetate 
• 371-41-5 4-Fluorophenol 
• 74-86-2 acetylene 
• 106-93-4 ethylene dibromide 
• 332-48-9 2-(4-fluorophenoxy)-ethylbromide 
• 865-47-4 potassium tert-butylate 

Downstream Products

• 333-09-5 2-(4-fluoro-phenoxy)-cyclopropanecarboxylic acid ethyl ester 
• 371-41-5 4-Fluorophenol 
• 1443532-78-2 [1-(4-fluorophenoxy)ethyl] bis(4-methoxyphenethyl)phosphinothioselenoate 
• 1443532-79-3 [1-(4-fluorophenoxy)ethyl] bis(4-methoxyphenethyl)phosphinoselenothioate 

Relevant articles and documents

Reductive C-O, C-N, and C-S Cleavage by a Zirconium Catalyzed Hydrometalation/β-Elimination Approach

A zirconium catalyzed reductive cleavage of Csp3 and Csp2 carbon-heteroatom bonds is reported that makes use of a tethered alkene functionality as a traceless directing group. The reaction is successfully demonstrated on C-O, C-N, and C-S bonds and proposed to proceed via a hydrozirconation/β-heteroatom elimination sequence of an in situ formed zirconium hydride catalyst. The positional isomerization of the catalyst further enables the cleavage of homoallylic ethers and the removal of terminal allyl and propargyl groups.