35189-94-7Relevant articles and documents
DIETHYL-1-MAGNESIUM CHLORIDE METHANEPHOSPHONATE, A NOVEL GRIGNARD REAGENT AND ITS USE IN ORGANIC SYNTHESIS
Coutrot, P.,Youssefi-Tabrizi, M.,Grison, C.
, p. 13 - 18 (1986)
Diethyl-1-magnesium chloride methanephosphonate was obtained by an exchange reaction between diethyliodo methanephosphonate and isopropylmagnesium chloride in THF at -70 deg.C.Reactions of this novel Grignard reagent with various electrophiles are described, and compared with those of the analogous lithium or copper derivatives.Diethyl-1-magnesium chloride methanephosphonate is especially reactive towards phenylselenium halides and halogens.