352-12-5Relevant articles and documents
PROCESSES FOR FLUORINATION
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Paragraph 0179; 0184; 0214-0215; 0218, (2021/04/10)
The present technology relates to fluorination reactions. Specifically, processes useful for making the fungicide compound, DFT are disclosed. More broadly, also disclosed herein are processes useful for deoxyfluorination at the α-aromatic position of a given compound.
PROCESSES FOR FLUORINATION
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Paragraph 0188, (2020/03/05)
The present technology relates to fluorination reactions. Specifically, processes useful for making the fungicide compound, DFT are disclosed. More broadly, also disclosed herein are processes useful for deoxyfluorination at the α-aromatic position of a given compound.
Expanding the repertoire of cyclopropenium ion phase transfer catalysis: Benzylic fluorination
Dempsey, Katie,Mir, Roya,Smajlagic, Ivor,Dudding, Travis
, p. 3507 - 3511 (2018/05/25)
The application of cyclopropenium ion as a phase transfer catalyst for benzylic fluorination in high yields is reported. Integral to the mechanisms of these fluorination reactions was the role of in situ derived cyclopropenium fluoride complexes, the existence of which was supported by 1H, 19F NMR and UV–Vis spectroscopy. Density functional theory calculations were applied to gain insight into the mechanism of these reactions.