35207-76-2

Basic information

• Product Name: Bicyclo[6.1.0]non-2-ene-9,9-dicarboxylic acid, dimethyl ester
• CAS NO: 35207-76-2
• Molecular Formula: C13H18O4
• Molecular Weight: 238.284
• Mol File: 35207-76-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Bicyclo[6.1.0]non-2-ene-9,9-dicarboxylic acid, dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[6.1.0]non-2-ene-9,9-dicarboxylic acid, dimethyl ester(35207-76-2)
• EPA Substance Registry System: Bicyclo[6.1.0]non-2-ene-9,9-dicarboxylic acid, dimethyl ester(35207-76-2)

Safety Data

• Hazardous Substances Data: 35207-76-2(Hazardous Substances Data)

Upstream product

• 6773-29-1 dimethyl diazomalonate 
• 3806-59-5 1,3-cyclooctadiene 

Relevant articles and documents

Photoredox catalysed allylic trifluoromethylation via ring opening of vinyl cyclopropanes using Langlois reagent

Trifluoromethylation of vinylcyclopropanes (VCPs) has been developed under mild reaction conditions to synthesize allylic trifluoromethylated derivatives with high yield and E/Z selectivity using visible light photo-redox catalysis and Langlois reagent (CF3SO2Na) as a trifluoromethylation source. Further, we demonstrate a gram scale synthesis procedure for a trifluoromethylation of vinylcyclopropane.