35216-17-2Relevant articles and documents
SOLVATION EFFECTS IN 1,3-DIPOLAR CYCLOADDITION
Kiselev, V. D.,Malkov, V. B.,Konovalov, A. I.
, p. 1736 - 1741 (2007/10/02)
The changes in the enthalpy of solvation of the transition state for the 1,3-dipolar cycloaddition of C,N-diphenylnitrone with N-(4-bromophenyl)maleimide in a series of solvents were determined in a kinetic and thermochemical study.From comparison with an analogous analysis of the enthalpy of solvation of the transition state in the Diels-Alder reaction it follows that these changes are fairly large and are similar to a significant degree in both cases.