3587-84-6Relevant articles and documents
A NEW AND SIMPLE SYNTHESIS OF ALKOXY- AND ARYLOXYMETHYLLITHIUM REAGENTS (ROCH2Li)
Corey, E. J.,Eckrich, Thomas M.
, p. 3163 - 3164 (1983)
A series of halomethyl alkyl and aryl ethers can be converted to the corresponding organolithium reagents (ROCH2Li) in a one-flask operation by sequential treatment (1) with stannous chloride-lithium bromide complex in tetrahydrofuran (THF) and (2) with n-butyllithium.
Enantiopure encaged Verkade's superbases: Synthesis, chiroptical properties, and use as chiral derivatizing agent
Yang, Jian,Chatelet, Bastien,Hérault, Damien,Dufaud, Véronique,Robert, Vincent,Grass, Stéphane,Lacour, Jér?me,Vanthuyne, Nicolas,Jean, Marion,Albalat, Muriel,Dutasta, Jean-Pierre,Martinez, Alexandre
, p. 139 - 146 (2019/12/27)
Verkade's superbases, entrapped in the cavity of enantiopure hemicryptophane cages, have been synthesized with enantiomeric excess (ee) superior to 98%. Their absolute configuration has been determined by using electronic circular dichroism (ECD) spectros
Aerobic Photooxidative Synthesis of β-Alkoxy Monohydroperoxides Using an Organo Photoredox Catalyst Controlled by a Base
Asano, Yuya,Nagasawa, Yoshitomo,Yamaguchi, Eiji,Itoh, Akichika
, p. 409 - 412 (2018/02/21)
Transition-metal-free synthesis of β-alkoxy monohydroperoxides via aerobic photooxidation using an acridinium photocatalyst was developed. This method enables the synthesis of some novel hydroperoxides. The peroxide source is molecular oxygen, which is cost-effective and atomically efficient. Magnesium oxide plays an important role as a base in the catalytic system.
