36132-68-0Relevant articles and documents
Oxidative Rearrangement of Primary Amines Using PhI(OAc)2 and Cs2CO3
Yamakoshi, Wataru,Arisawa, Mitsuhiro,Murai, Kenichi
supporting information, (2019/05/08)
An oxidative rearrangement of primary amines mediated by a hypervalent iodine(III) reagent is herein reported. The combination of PhI(OAc)2 and Cs2CO3 proves highly efficient at inducing the direct 1,2-C to N migration of primary amines, which can be applied to the preparation of both acyclic and cyclic amines. A mechanistic study shows that the rearrangement proceeds via a concerted mechanism.
Transition Metal Complexes and Preparation Methods Thereof
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Page/Page column 12, (2009/02/11)
The present invention provides a novel mononuclear transition metal compound, a novel binuclear transition metal compound, a novel organic amine or phosphorous compound, and a method for preparing the same. The mononuclear transition metal compound accord
CATALYST COMPOSITION COMPRISING GROUP 4 TRANSITION METAL COMPLEXES AND METHOD FOR PREPARING POLYOLEFINS USING THE SAME
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Page/Page column 19, (2010/11/28)
The present invention relates to a catalyst composition comprising a novel structure of a Group 4 transition metal compound, to a method for preparing the same, and to a method for preparing a polyolefin using the catalyst composition. The method for prep